Theory does not support an osmaoxetane intermediate in the osmium-catalyzed dihydroxylation of olefins

被引：115

作者：

Dapprich, S

Ujaque, G

Maseras, F

Lledos, A

Musaev, DG

Morokuma, K

机构：

[1] EMORY UNIV, CHERRY L EMERSON CTR SCI COMPUTAT, ATLANTA, GA 30322 USA

[2] UNIV AUTONOMA BARCELONA, DEPT QUIM, UNITAT QUIM FIS, E-08193 BELLATERRA, BARCELONA, SPAIN

[3] UNIV MONTPELLIER 2, UMR 5636, LAB STRUCT & DYNAM SYST MOL & SOLIDES, F-34095 MONTPELLIER 5, FRANCE

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1996年 / 118卷 / 46期

关键词：

D O I：

10.1021/ja9625992

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

[No abstract available]

引用

收藏

页码：11660 / 11661

页数：2

相关论文

共 24 条

[21] PIDUN U, 1996, IN PRESS ANGEW CHEM
[22] CHROMYL CHLORIDE OXIDATIONS OF OLEFINS - POSSIBLE ROLE OF ORGANOMETALLIC INTERMEDIATES IN OXIDATIONS OF OLEFINS BY OXO TRANSITION-METAL SPECIES
SHARPLESS, KB
TERANISHI, AY
BACKVALL, JE
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1977, 99 (09) : 3120 - 3128
[23] MECHANISM OF THE ENANTIOSELECTIVE DIHYDROXYLATION OF OLEFINS BY OSO4 IN THE PRESENCE OF CHIRAL BASES
VELDKAMP, A
FRENKING, G
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1994, 116 (11) : 4937 - 4946
[24] A NEW MODEL FOR THE STEREOSELECTIVITIES OF DIHYDROXYLATIONS OF ALKENES BY CHIRAL DIAMINE COMPLEXES OF OSMIUM TETRAOXIDE
WU, YD
WANG, Y
HOUK, KN
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1992, 57 (05) : 1362 - 1369