Synthesis and characterisation of a bis(silyloxy)tin(IV) porphyrin

被引：17

作者：

Langford, SJ ^{[1
]}

Latter, MJ

Beckmann, J

机构：

[1] Monash Univ, Sch Chem, Melbourne, Vic 3800, Australia

[2] Free Univ Berlin, Inst Chem Inorgan & Analyt Chem, D-14195 Berlin, Germany

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2005年 / 8卷 / 10期

关键词：

Sn(IV) porphyrins; silanols; complexations; NMR spectroscopy;

D O I：

10.1016/j.inoche.2005.07.005

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Bis(hydroxy)tin(IV) tetraphenylporphyrin (Sn(IV)TPP(OH)2, 2) condenses with two equivalents of tris(tert-butoxy)silanol (HOSi((OBu)-Bu-t)(3), 3) to form complex 2.3(2)in toluene. The product, which is air and moisture stable, has been characterised by H-1, Si-29 and Sn-119 NMR spectroscopy and mass spectrometry. Application of this reaction in producing novel photochromic glasses is also discussed. (c) 2005 Elsevier B.V. All rights reserved.

引用

页码：920 / 923

页数：4

共 11 条

[1] The coordination chemistry of tin porphyrin complexes [J].

Arnold, DP ;

Blok, J .

COORDINATION CHEMISTRY REVIEWS, 2004, 248 (3-4) :299-319

[2]

ARNOLD DP, 1998, J CHEM EDUC, V65, P1111

[3]

Ciamician G, 1912, Science, V36, P385, DOI 10.1126/science.36.926.385

[4] Efficient formation of lipophilic dihydroxotin(IV) porphyrins and bis-porphyrins [J].

Crossley, MJ ;

Thordarson, P ;

Wu, RAS .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 2001, (18) :2294-2302

[5] Self-assembling mixed porphyrin trimers - the use of diaxial Sn(IV)porphyrin phenolates as an organising precept [J].

Fallon, GD ;

Langford, SJ ;

Lee, MAP ;

Lygris, E .

INORGANIC CHEMISTRY COMMUNICATIONS, 2002, 5 (09) :715-718

[6] Metalloporphyrin molecular sieves based on tin(IV)porphyrin phenolates [J].

Fallon, GD ;

Lee, MAP ;

Langford, SJ ;

Nichols, PJ .

ORGANIC LETTERS, 2002, 4 (11) :1895-1898

[7] Dye-sensitized solar cells [J].

Grätzel, M .

JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY C-PHOTOCHEMISTRY REVIEWS, 2003, 4 (02) :145-153

[8] Solar cell efficiency tables (version 18) [J].

Green, MA ;

Emery, K ;

King, DL ;

Igari, S ;

Warta, W .

PROGRESS IN PHOTOVOLTAICS, 2001, 9 (04) :287-293

[9] Six-sided heptaporphyrin array: Towards a nano-sized cube [J].

Langford, SJ ;

Woodward, CP .

COLLECTION OF CZECHOSLOVAK CHEMICAL COMMUNICATIONS, 2004, 69 (05) :996-1008

[10]

LANGFORD SJ, 2001, J INCL PHENOM MACRO, P135

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