Urothermal in situ ligand synthesis to fabricate a metal-organic framework with (3,4)-connected tfi topology

被引：15
作者：
Yang, Hui [1 ,2 ]
Li, Tie Hu [2 ]
Kang, Yao [1 ]
Wang, Fei [1 ]
机构：
[1] Chinese Acad Sci, State Key Lab Struct Chem, Fujian Inst Res Struct Matter, Fuzhou 35002, Fujian, Peoples R China
[2] Northwestern Polytech Univ, Sch Mat Sci & Engn, Xian 710072, Peoples R China
来源：
INORGANIC CHEMISTRY COMMUNICATIONS | 2011年 / 14卷 / 11期
关键词：
Urothermal synthesis; 2-imidazolidinone; Topology; Metal organic framework; Crystal structure; NETS; PHOSPHOR;
D O I：
10.1016/j.inoche.2011.07.009
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A new 3D metal-organic framework [Cu(en)(ntd)](e-urea)(H2O) (1; en = 1.2-ethylenediamine, ntd = 1,4-Naphthalenedicarboxylic acid, e-urea = 2-imidazolidinone hemihydrate), has been synthesized by urothermal method. Structural analysis shows that compound 1 possesses unprecedented (3,4)-connected tfi topology. 2-imidazolidinone, one of the urea derivatives, plays multiple roles in the self-assembly of compound 1. (C) 2011 Elsevier B.V. All rights reserved.
引用
收藏
页码：1695 / 1697
页数：3
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