Emission tuning in Re(I) complexes: Expanding heterocyclic ligands and/or introduction of perfluorinated ligands

被引：8

作者：

Abramov, Pavel A. ^{[1
,2
]}

Brylev, Konstantin A. ^{[1
,2
]}

Vorob'ev, Aleksei Yu. ^{[2
,3
]}

Gatilov, Yuriy V. ^{[2
,3
]}

Borodkin, Gennadiy I. ^{[2
,3
]}

Kitamura, Noboru ^{[4
]}

Sokolov, Maxim N. ^{[1
,2
,5
]}

机构：

[1] Nikolaev Inst Inorgan Chem, 3 Akad Lavrentiev Ave, Novosibirsk 630090, Russia

[2] Novosibirsk State Univ, 2 Pirogova Str, Novosibirsk 630090, Russia

[3] Vorozhtsov Novosibirsk Inst Organ Chem SB RAS, 9 Akad Lavrentiev Ave, Novosibirsk 630090, Russia

[4] Hokkaido Univ, Dept Chem, Fac Sci, Sapporo, Hokkaido 0600810, Japan

[5] Kazan Fed Univ, Kremlyovskaya St 18, Kazan 420008, Russia

来源：

POLYHEDRON | 2017年 / 137卷

关键词：

Rhenium; Diimine; Luminescence; Perfluorinated ligands;

D O I：

10.1016/j.poly.2017.08.046

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reactions of new heterocyclic ligands 2-(pyridin-2-yl)-[1,2,4]triazolo[1,5-a]quinolin-9-ol (L-OH), 2-(pyridin-2-yl)-[1,2,4]triazolo[1,5-a][1,10]phenanthroline (L-Py) and 2-methyl-[1,2,4]triazolo[1,5-a][1,10] phenanthroline (L-Me) with [Re(CO)(5)Br] in toluene afforded the complexes of the general formula [(L) Re(CO)(3)Br]. Substitution of the Br- ligand in [(L)Re(CO)(3)Br] by C3F7COO- leads to [(L)Re (CO)(3)(OOCC3F7)] and results in increased emission lifetime. (C) 2017 Elsevier Ltd. All rights reserved.

引用

页码：231 / 237

页数：7

共 7 条

[1]

Fedin P., 2011, DALTON T, V40, P6375

[2] New chloro- and trifluoroacetato tricarbonylrhenium(I) complexes with a N,N′-bis(benzophenone)-1,2-diiminoethane Schiff base ligand:: Spectral and structural studies [J].

Kia, Reza ;

Mirkhani, Valiollah ;

Kalman, Majos ;

Deak, Andrea .

POLYHEDRON, 2007, 26 (08) :1711-1716

[3]

Kitamura, 2013, DALTON T, V42, P12947

[4] Non-steroidal pregnancy-terminating agents:: Design, synthesis and structure-activity relationships of 2-aryl-1,2,4-triazolo[1,5-a]pyridine [J].

Liu, T ;

Hu, YZ .

BIOORGANIC & MEDICINAL CHEMISTRY LETTERS, 2002, 12 (17) :2411-2413

[5] Multi-mode molecular switching properties and functions of azo-conjugated metal complexes [J].

Nishihara, H .

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 2004, 77 (03) :407-428

[6]

Pac JJ, 1994, INORG CHEM, V33, P4712

[7]

Shiina S., 2009, PHYS CHEM CHEM PHYS, V11, P9850

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