Valence change of praseodymium in Pr0.5Ca0.5CoO3 investigated by x-ray absorption spectroscopy

被引：55

作者：

Herrero-Martin, J. ^{[1
]}

Garcia-Munoz, J. L. ^{[1
]}

Valencia, S. ^{[2
]}

Frontera, C. ^{[1
]}

Blasco, J. ^{[3
]}

Baron-Gonzalez, A. J. ^{[1
]}

Subias, G. ^{[3
]}

Abrudan, R. ^{[4
]}

Radu, F. ^{[2
]}

Dudzik, E. ^{[2
]}

Feyerherm, R. ^{[2
]}

机构：

[1] CSIC, Inst Ciencia Mat Barcelona, E-08193 Barcelona, Spain

[2] Hemholtz Zentrum Berlin Mat & Energie, D-12489 Berlin, Germany

[3] Univ Zaragoza, CSIC, Inst Ciencia Mat Aragon, E-50009 Zaragoza, Spain

[4] Ruhr Univ Bochum, Inst Expt Phys Festkorperphys, D-44780 Bochum, Germany

来源：

PHYSICAL REVIEW B | 2011年 / 84卷 / 11期

关键词：

SPIN-STATE TRANSITION; NEAR-EDGE STRUCTURE; ELECTRONIC-STRUCTURE; MAGNETIC-PROPERTIES; HIGH-PRESSURE; LACOO3; PR; SUPERCONDUCTIVITY; DIFFRACTION; PEROVSKITE;

D O I：

10.1103/PhysRevB.84.115131

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

X-ray absorption spectroscopy measurements in Pr0.5Ca0.5CoO3 were performed at the Pr M-4,M-5, Pr L-3, and Ca L-2,L-3 absorption edges as a function of temperature below 300 K. Ca spectra show no changes down to 10 K while a noticeable thermally dependent evolution takes place at the Pr edges across the metal-insulator transition. Spectral changes are analyzed by different methods, including multiple scattering simulations, which provide quantitative details on an electron loss at Pr 4f orbitals. We conclude that in the insulating phase a fraction [15(+/- 5)%] of Pr3+ undergoes a further oxidation to adopt a hybridized configuration composed of an admixture of atomiclike 4f(1) states (Pr4+) and f-symmetry states on the O 2p valence band (Pr3+ (L) under bar states) indicative of a strong 4f-2p interaction.

引用

页数：6

共 36 条

[1] LOCALIZED MAGNETIC STATES IN METALS
ANDERSON, PW
[J]. PHYSICAL REVIEW, 1961, 124 (01): : 41 - &
[2] Role of A-site cations in the metal-insulator transition in Pr0.5Ca0.5CoO3-γ (γ≈0)
Baron-Gonzalez, A. J.
Frontera, C.
Garcia-Munoz, J. L.
Blasco, J.
Ritter, C.
[J]. PHYSICAL REVIEW B, 2010, 81 (05)
[3] SPECIFIC INTERMEDIATE-VALENCE STATE OF INSULATING 4F COMPOUNDS DETECTED BY L3 X-RAY ABSORPTION
BIANCONI, A
MARCELLI, A
DEXPERT, H
KARNATAK, R
KOTANI, A
JO, T
PETIAU, J
[J]. PHYSICAL REVIEW B, 1987, 35 (02) : 806 - 812
[4] Resonant X-ray fluorescence spectroscopy of correlated systems: A probe of charge-transfer excitations
Butorin, SM
Mancini, DC
Guo, JH
Wassdahl, N
Nordgren, J
Nakazawa, M
Tanaka, S
Uozumi, T
Kotani, A
Ma, Y
Myano, KE
Karlin, BA
Shuh, DK
[J]. PHYSICAL REVIEW LETTERS, 1996, 77 (03) : 574 - 577
[5] The low-temperature phase separation in Pr0.5Ca0.5CoO3
Chichev, A.
Hejtmanek, J.
Jirak, Z.
Knizek, K.
Marysko, M.
Dlouha, M.
Vratislav, S.
[J]. JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS, 2007, 316 (02) : E728 - E730
[6] de Groot F, 2008, ADV CONDENS MAT SCI, V6, P1
[7] The new HMI beamline MAGS: an instrument for hard X-ray diffraction at BESSY
Dudzik, Esther
Feyerherm, Ralf
Diete, Wolfgang
Signorato, Riccardo
Zilkens, Christopher
[J]. JOURNAL OF SYNCHROTRON RADIATION, 2006, 13 : 421 - 425
[8] Selective spin-state switch and metal-insulator transition in GdBaCo2O5.5 -: art. no. 180405
Frontera, C
García-Muñoz, JL
Llobet, A
Aranda, MAG
[J]. PHYSICAL REVIEW B, 2002, 65 (18) : 1 - 4
[9] On the mechanism of the spin state transition of (Pr1-ySmy)1-xCaxCoO3
Fujita, T
Kawabata, S
Sato, M
Kurita, N
Hedo, M
Uwatoko, Y
[J]. JOURNAL OF THE PHYSICAL SOCIETY OF JAPAN, 2005, 74 (08) : 2294 - 2300
[10] Transport and magnetic studies on the spin state transition of Pr1-xCaxCoO3 up to high pressure
Fujita, T
Miyashita, T
Yasui, Y
Kobayashi, Y
Sato, M
Nishibori, E
Sakata, M
Shimojo, Y
Igawa, N
Ishii, Y
Kakurai, K
Adachi, T
Ohishi, Y
Takata, M
[J]. JOURNAL OF THE PHYSICAL SOCIETY OF JAPAN, 2004, 73 (07) : 1987 - 1997

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