High temperature pH sensing and O2- conduction properties of electrophoretically fabricated ceria composites

被引:14
作者
Hamagami, J
Inda, Y
Umegaki, T
Yamashita, K
机构
[1] Tokyo Metropolitan Univ, Dept Ind Chem, Tokyo 19203, Japan
[2] Tokyo Med & Dent Univ, Inst Med & Dent Engn, Chiyoda Ku, Tokyo 101, Japan
关键词
pH; ionic conductivity - oxygen; cerium oxide; composites;
D O I
10.1016/S0167-2738(98)00287-2
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Sm2O3-doped ceria (SC) ceramics, in which an yttria-stabilized zirconia (YSZ) thin layer of 2 mu m in thickness was inserted, was fabricated by the electrophoretic lamination method followed by sintering. The pH sensing properties of the SC/YSZ/SC composite ceramics were examined: the result indicated an approximate Nernstian response of -65.3 mV/pH and the response time of within 50 s at 353 K. The electrolytic properties of SC/YSZ/SC composites were also studied using solid oxide fuel cells (SOFCs) and oxygen sensors. (C) 1998 Elsevier Science B.V. All rights reserved.
引用
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页码:235 / 239
页数:5
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