Crystal structure of Ir(acac-O,O)2(acac-C3)(pyridine)

被引：4

作者：

Chang, Q. ^{[1
]}

Chen, J. ^{[1
]}

Xie, M. ^{[2
]}

Liu, W. ^{[1
]}

Yu, Y. ^{[1
]}

Ye, Q. ^{[1
]}

Chen, X. ^{[1
]}

机构：

[1] Kunming Inst Precious Met, State Key Lab Adv Technol, PGM, Kunming 650106, Peoples R China

[2] Yunnan Univ, Sch Chem, Kunming 650031, Peoples R China

来源：

JOURNAL OF STRUCTURAL CHEMISTRY | 2011年 / 52卷 / 04期

关键词：

Iridium; acetylacetone; pyridine; gamma-C-bonded beta-diketone complexes; crystal structure; C-H; ANTI-MARKOVNIKOV; COMPLEX;

D O I：

10.1134/S0022476611040299

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Ir(acac-O,O)(2)(acac-C-3)(pyridine), 1 is synthesized, and its crystal structure is determined by single crystal X-ray diffraction. In the complex, the central Ir(III) atom displays a distorted octahedral geometry wherein the equatorial positions are occupied by four oxygen atoms of two acetylacetone ligands, and the apical positions are coordinated by a carbon atom of one acetylacetone ligand and a nitrogen atom of pyridine.

引用

页码：824 / 827

页数：4

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