Highly sensitive and selective cyanide detection via Cu2+ complex ligand exchange

被引:90
作者
Gee, Hyuk-Chan [1 ]
Lee, Chi-Hwa [1 ]
Jeong, Young-Hwan [1 ]
Jang, Woo-Dong [1 ]
机构
[1] Yonsei Univ, Dept Chem, Seoul 120749, South Korea
基金
新加坡国家研究基金会;
关键词
NITRIC-OXIDE DETECTION; FLUORESCENT-PROBE; AQUEOUS-SOLUTION; COLORIMETRIC CHEMOSENSOR; ANION RECOGNITION; COPPER-COMPLEXES; METAL-IONS; IN-VIVO; WATER; RECEPTORS;
D O I
10.1039/c1cc14963f
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A new type of fluorescent probe (1) with two triazole groups that are conjugated with a carbazole moiety was synthesized by a Cu-I-catalyzed alkyne-azide click reaction for the selective and sensitive detection of cyanide via fluorescence enhancement by ligand exchange and metal ion removal.
引用
收藏
页码:11963 / 11965
页数:3
相关论文
共 54 条
[1]   What anions do to N-H-containing receptors [J].
Amendola, Valeria ;
Esteban-Gomez, David ;
Fabbrizzi, Luigi ;
Licchelli, Maurizio .
ACCOUNTS OF CHEMICAL RESEARCH, 2006, 39 (05) :343-353
[2]  
[Anonymous], 1999, Ullmann's Encyclopedia of Industrial Chemistry
[3]   Enhanced fluorescence cyanide detection at physiologically lethal levels: Reduced ICT-based signal transduction [J].
Badugu, R ;
Lakowicz, JR ;
Geddes, CD .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (10) :3635-3641
[4]  
Baird C.i Cann., 2005, Environmental chemistry
[5]  
Baskin S.I., 1997, TXB MILITARY MED MED, P271
[6]  
Beer P.D., 2001, ANGEW CHEM, V113, P502
[7]  
Beer PD, 2001, ANGEW CHEM INT EDIT, V40, P486, DOI 10.1002/1521-3773(20010202)40:3<486::AID-ANIE486>3.0.CO
[8]  
2-P
[9]   A near-infrared fluorescent sensor for detection of cyanide in aqueous solution and its application for bioimaging [J].
Chen, Xiaoqiang ;
Nam, Seong-Won ;
Kim, Gun-Hee ;
Song, Nari ;
Jeong, Yongsuk ;
Shin, Injae ;
Kim, Seog K. ;
Kim, Jinheung ;
Park, Sungsu ;
Yoon, Juyoung .
CHEMICAL COMMUNICATIONS, 2010, 46 (47) :8953-8955
[10]   A highly selective cyanide sensing in water via fluorescence change and its application to in vivo imaging [J].
Chung, So-Young ;
Nam, Seong-Won ;
Lim, Jeesun ;
Park, Sungsu ;
Yoon, Juyoung .
CHEMICAL COMMUNICATIONS, 2009, (20) :2866-2868