A new cyclobutane-substituted Schiff base ligand and its Co(II), Cu(II), Ni(II), and Zn(II) complexes

被引:10
|
作者
Çukurovali, A [1 ]
Yilmaz, I [1 ]
Ahmedzade, M [1 ]
Özmen, H [1 ]
机构
[1] Firat Univ, Fac Arts & Sci, Dept Chem, TR-23119 Elazig, Turkey
来源
SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY | 2001年 / 31卷 / 02期
关键词
D O I
10.1081/SIM-100002045
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
A new ligand, 4-(1-phenyl-1-methylcyclobutyl-3-yl)-2-(2-hydroxy-1-naphtylidene)thiazole (LH), has been synthesized starting from 1-phenyl-1-methyl-3-(2-chloro-1-oxoethyl) cyclobutane, thiourea and 2-hydroxy-1-napthalaldehyde. Mononuclear complexes with a metal-ligand ratio of 1:2 have been prepared with Co(II), Cu(II), Ni(II) and Zn(II) salts. Structures of the ligand and its complexes are suggested based on elemental analyses, IR, C-13 and H-1 NMR spectra, magnetic susceptibility measurements and thermogravimetric analyses (TGA).
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页码:255 / 262
页数:8
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