Metal dicarboxylates: new anode materials for lithium-ion batteries with good cycling performance

被引:28
作者
Fei, Hailong [1 ,2 ]
Liu, Xin [1 ]
Li, Zhiwei [1 ]
Feng, Wenjing [1 ]
机构
[1] Fuzhou Univ, Coll Chem, Univ Town Fuzhou 350116, Fujian, Peoples R China
[2] Nankai Univ, Key Lab Adv Energy Mat Chem, Minist Educ, Tianjin 300071, Peoples R China
基金
中国国家自然科学基金;
关键词
OXYGEN COORDINATION COMPLEX; ELECTROCHEMICAL PERFORMANCE; ORGANIC FRAMEWORKS; CRYSTAL-STRUCTURE; FACILE SYNTHESIS; VANADIUM BRONZE; LI; PROPERTY; POLYMER;
D O I
10.1039/c5dt00500k
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
A simple and versatile method for the preparation of manganese coordination polymers [Mn(3,5-PDC)center dot 2H(2)O] (3,5-H2PDC = 3,5-pyridinedicarboxylic acid) and Mn 2,5-furandicarboxylate which goes via a simple hydrothermal route is developed and the coordination polymers are tested as novel high-energy anode materials for lithium-ion batteries for the first time. [Mn(3,5-PDC)center dot 2H(2)O] shows a high discharge capacity of 583.9 mA h g(-1) for the fourth cycle between a 0.05-3.0 V voltage limit at a discharge current density of 100 mA g(-1). A reversible capacity of 554.0 mA h g(-1) is retained after 240 cycles with a capacity retention of 94.8% while Mn 2,5-furandicarboxylate shows a high discharge capacity of 467.3 mA h g(-1) for the second cycle and a reversible capacity of 436.6 mA h g(-1) is retained after 206 cycles with a capacity retention of 93.4%.
引用
收藏
页码:9909 / 9914
页数:6
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