A low-temperature electrolyte for lithium-ion batteries

被引:58
作者
Li, Shiyou [1 ]
Li, Xiaopeng [1 ]
Liu, Jinliang [1 ]
Shang, Zhichao [1 ]
Cui, Xiaoling [1 ]
机构
[1] Lanzhou Univ Technol, Coll Petrochem Technol, Lanzhou 730050, Peoples R China
关键词
Lithium-ion batteries; Low temperature; Electrolyte; Mixture salt; Electrochemical performance; ELECTROCHEMICAL PERFORMANCES; SULFOLANE; CELLS; DIFLUORO(OXALATO)BORATE; BIS(OXALATE)BORATE; CARBONATES; SOLVENT;
D O I
10.1007/s11581-014-1275-0
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
In this paper, the electrochemical performance of a new low-temperature electrolyte, 0.9 mol L-1 lithium oxalyldifluoroborate (LiODFB)/LiBF4 (5.365:1, by mass) mixed salts in the ethylene carbonate (EC)/dimethyl sulfite (DMS)/ethyl methyl carbonate (EMC) mixed solvent (1:1:3, by volume, the same below), is studied to seek the promising candidate for advanced low-temperature lithium-ion batteries (LIBs). The results show that LIBs using this new electrolyte can be operable well at temperature below -20 A degrees C. This is useful to expand the application range of LIBs, especially at specific low-temperature environments, such as military and aerospace applications.
引用
收藏
页码:901 / 907
页数:7
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