(N-Butyl-N-phenyldithiocarbamato-κS)triphenyltin(IV)

被引：1

作者：

Kamaludin, Nurul Farahana ^{[2
]}

Baba, Ibrahim ^{[3
]}

Awang, Normah ^{[2
]}

Tahir, Mohamed Ibrahim Mohamed ^{[4
]}

Tiekink, Edward R. T. ^{[1
]}

机构：

[1] Univ Malaya, Dept Chem, Kuala Lumpur 50603, Malaysia

[2] Univ Kebangsaan Malaysia, Environm Hlth Programme, Fac Allied Hlth Sci, Kuala Lumpur 50300, Malaysia

[3] Univ Kebangsaan Malaysia, Sch Chem Sci & Food Technol, Fac Sci & Technol, Bangi 43600, Malaysia

[4] Univ Putra Malaysia, Dept Chem, Serdang 43400, Malaysia

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2011年 / 67卷

关键词：

D O I：

10.1107/S1600536811012426

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The title compound, [Sn(C6H5)(3)(C11H14NS2)], features a tetrahedrally coordinated Sn atom, as the dithiocarbamate ligand coordinates in a monodentate fashion. Due to the proximity of the non-coordinating thione S atom, distortions from ideal tetrahedral geometry about the metal atom are evident with the widest C-Sn-S angle being 117.26 (5)degrees. In the crystal, molecules are linked by C-H center dot center dot center dot S interactions, which generate helical supramolecular chains along the b axis.

引用

页码：M555 / U510

页数：13

共 7 条

[1] [Anonymous], 2010, CRYSALIS PRO
[2] (N-sec-Butyl-N-n-propyldithiocarbamato-κ2S,S′)triphenyltin(IV)
Awang, Normah
Baba, Ibrahim
Yamin, Bohari M.
Ng, Seik Weng
Tiekink, Edward R. T.
[J]. ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2010, 66 : M1144 - U948
[3] Brandenburg K., 2006, DIAMOND
[4] Farrugia L.J., 1997, J. Appl. Crystallogr., V30, P565, DOI [10.1107/S0021889897003117, DOI 10.1107/S0021889897003117]
[5] A short history of SHELX
Sheldrick, George M.
[J]. ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES, 2008, 64 : 112 - 122
[6] Tin dithiocarbamates: applications and structures
Tiekink, Edward R. T.
[J]. APPLIED ORGANOMETALLIC CHEMISTRY, 2008, 22 (09) : 533 - 550
[7] publCIF: software for editing, validating and formatting crystallographic information files
Westrip, Simon P.
[J]. JOURNAL OF APPLIED CRYSTALLOGRAPHY, 2010, 43 : 920 - 925

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