KF/Nano-clinoptilolite Catalyzed Aldol-Type Reaction of Aldehydes with Ethyl Diazoacetate

被引：21
作者：
Balou, Javad [1 ]
Khalilzadeh, Mohammad A. [1 ,2 ]
Zareyee, Dariush [1 ]
机构：
[1] Islamic Azad Univ, Qaemshahr Branch, Dept Chem, Qaemshahr, Iran
[2] North Carolina State Univ, Dept Biomat, Coll Nat Resources, Raleigh, NC 27695 USA
来源：
CATALYSIS LETTERS | 2017年 / 147卷 / 10期
关键词：
KF/nano-clinoptilolite; Aldol-type reaction; Ethyl diazoacetate; alpha-Diazo carbonyl derivatives; ALPHA-DIAZOCARBONYL COMPOUNDS; BETA-HYDROXY ESTERS; SOLVENT-FREE CONDITIONS; EFFICIENT SOLID BASE; CONDENSATION; ACYLDIAZOMETHANES; DERIVATIVES; WATER; KF/CLINOPTILOLITE; GENERATION;
D O I：
10.1007/s10562-017-2158-6
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Potassium fluoride supported on nano-clinoptilolite (KF/CP NPs) was used as an excellent catalytic system for direct aldol-type condensation of aldehydes with ethyl diazoacetate under solvent-less conditions. A variety of alpha-diazo carbonyl derivatives were prepared in good to excellent yields in short reaction times.
引用
收藏
页码：2612 / 2618
页数：7
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