KF/Nano-clinoptilolite Catalyzed Aldol-Type Reaction of Aldehydes with Ethyl Diazoacetate

被引：21

作者：

Balou, Javad ^{[1
]}

Khalilzadeh, Mohammad A. ^{[1
,2
]}

Zareyee, Dariush ^{[1
]}

机构：

[1] Islamic Azad Univ, Qaemshahr Branch, Dept Chem, Qaemshahr, Iran

[2] North Carolina State Univ, Dept Biomat, Coll Nat Resources, Raleigh, NC 27695 USA

来源：

CATALYSIS LETTERS | 2017年 / 147卷 / 10期

关键词：

KF/nano-clinoptilolite; Aldol-type reaction; Ethyl diazoacetate; alpha-Diazo carbonyl derivatives; ALPHA-DIAZOCARBONYL COMPOUNDS; BETA-HYDROXY ESTERS; SOLVENT-FREE CONDITIONS; EFFICIENT SOLID BASE; CONDENSATION; ACYLDIAZOMETHANES; DERIVATIVES; WATER; KF/CLINOPTILOLITE; GENERATION;

D O I：

10.1007/s10562-017-2158-6

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Potassium fluoride supported on nano-clinoptilolite (KF/CP NPs) was used as an excellent catalytic system for direct aldol-type condensation of aldehydes with ethyl diazoacetate under solvent-less conditions. A variety of alpha-diazo carbonyl derivatives were prepared in good to excellent yields in short reaction times.

引用

页码：2612 / 2618

页数：7

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