In Situ Formation of One-Dimensional Assemblies of Gold Nanoparticles in Confined Media

被引:2
|
作者
Carballido-Landeira, Jorge [1 ]
Goy-Lopez, Sonia [2 ]
Munuzuri, Alberto P. [1 ]
Taboada, Pablo [2 ]
Mosquera, Victor [2 ]
机构
[1] Univ Santiago de Compostela, Grp Fis No Lineal, Santiago De Compostela 15782, Spain
[2] Univ Santiago de Compostela, Fac Fis, Dept Fis Mat Condensada, Grp Fis Coloides & Polimeros, Santiago De Compostela 15782, Spain
关键词
nanomaterials; nanotubes; rearrangement; self-assembly; solvent effects; FACILE SYNTHESIS; AU NANOWIRES; NANOCRYSTALS; SUPERLATTICES; NANORODS; POLYMER; SURFACE; SIZE; SUPERSTRUCTURES; TEMPLATES;
D O I
10.1002/cphc.201100796
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The spontaneous in situ formation of one-dimensional (1D) assemblies of gold nanoparticles (NP) in oleylamine/bis(2-ethylhexyl) sulfosuccinate sodium salt/water/octane (OAm/AOT/w/o) microemulsions by exploiting both the aurophilic bonding between OAm and gold salt, and the interactions between OAm and AOT surfactant is presented. Control on the structure of the resulting assemblies is achieved by changing in the solvent quality, the [Au]/[AOT] molar ratio and the presence of different cosolutes. A possible mechanism of the formation of the 1D parallel Au NP arrays is proposed.
引用
收藏
页码:1347 / 1353
页数:7
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