Synthesis and structure of triphenylbismuth bis(1-adamantanecarboxylate)

被引：8

作者：

Sharutin, V. V. ^{[1
]}

Senchurin, V. S. ^{[1
]}

Sharutina, O. K. ^{[1
]}

机构：

[1] Blagoveshchensk State Pedag Univ, Blagoveshchensk 675000, Russia

来源：

RUSSIAN JOURNAL OF INORGANIC CHEMISTRY | 2011年 / 56卷 / 10期

关键词：

Dicarboxylates; Adamantyl; Carbonyl Oxygen Atom; Trigonal Bipyramid; Carboxylate Ligand;

D O I：

10.1134/S0036023611100202

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Triphenylbismuth bis(1-adamantanecarboxylate) was synthesized by reacting triphenylbismuth with 1-adamantanecarboxylic acid in the presence of hydrogen peroxide. In the complex, the coordination sphere of a bismuth atom is a trigonal bipyramid with C(Ph) atoms in the equatorial plane and O atoms in the apical positions. The Bi-C bond lengths are 2.213(4) (two bonds) and 2.222(5) ; two Bi-O bond lengths are 2.306(3) . The BiaEuro broken vertical bar O(=C) donor-acceptor interactions (2.716(3) ) occur in the molecule. The equatorial CBiC angle on the side of the BiaEuro broken vertical bar O(=C) contact is 157.1(2)A degrees.

引用

页码：1565 / 1567

页数：3

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