Rhodium-catalysed aryl transfer to aldehydes: counterion effects with nitrogen containing ligands

被引：88

作者：

Moreau, C ^{[1
]}

Hague, C ^{[1
]}

Weller, AS ^{[1
]}

Frost, CG ^{[1
]}

机构：

[1] Univ Bath, Dept Chem, Bath BA2 7AY, Avon, England

来源：

TETRAHEDRON LETTERS | 2001年 / 42卷 / 39期

关键词：

D O I：

10.1016/S0040-4039(01)01421-6

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Cationic rhodium complexes of certain nitrogen-containing ligands exhibit excellent catalytic activity in the addition of arylboronic acids to aldehydes. The counterion had a notable effect with the weakly coordinating carborane anion affording a highly active catalyst. (C) 2001 Elsevier Science Ltd. All rights reserved.

引用

页码：6957 / 6960

页数：4

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