New synthetic methodologies based on active transition metals

被引：37

作者：

Alonso, Francisco

Yust, Miguel ^{[1
,2
]}

机构：

[1] Univ Alicante, Fac Sci, Dept Organ Chem, Alicante 03080, Spain

[2] Univ Alicante, Inst Organ Synth, Alicante 03080, Spain

来源：

PURE AND APPLIED CHEMISTRY | 2008年 / 80卷 / 05期

关键词：

active metals; nickel; copper; iron; nanoparticles; reduction; alkylation of ketones with alcohols;

D O I：

10.1351/pac200880051005

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Active transition metals, namely, nickel, copper and iron, have been prepared by the reduction of the corresponding chlorides with lithium and a catalytic amount of an arene. These metals, in the form of nanoparticles, have found application in the reduction of a wide variety of functional groups as well as in the alkylation of methyl ketones with primary alcohols.

引用

页码：1005 / 1012

页数：8

共 32 条

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[3] A new straightforward and mild preparation of nickel(0) nanoparticles
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[4] Hydrodehalogenation of organic halides using the CuCl2.2H2O-Li-arene(cat.) combination
Alonso, F
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[5] The NiCl2-Li-arene(cat.) combination: A versatile reducing mixture
Alonso, F
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[6] Metal-mediated reductive hydrodehalogenation of organic halides
Alonso, F
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[7] The NiCl2-Li-arene (cat.) combination as reducing system, part 9:: Catalytic hydrogenation of organic compounds using the NiCl2-Li-(Naphthalene or polymer-supported naphthalene) (cat.) combination
Alonso, F
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Gómez, C
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[J]. ADVANCED SYNTHESIS & CATALYSIS, 2003, 345 (1-2) : 275 - 279
[8] Alonso F, 2003, SYNTHESIS-STUTTGART, P443
[9] Homocoupling of aryl iodides promoted by nickel(0) nanoparticles
Alonso, Francisco
Riente, Paola
Yus, Miguel
[J]. ARKIVOC, 2008, : 8 - 15
[10] Hydrogen-transfer reduction of carbonyl compounds promoted by nickel nanoparticles
Alonso, Francisco
Riente, Paola
Yus, Miguel
[J]. TETRAHEDRON, 2008, 64 (08) : 1847 - 1852

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