Recent Developments on Silicoaluminates and Silicoaluminophosphates in the Methanol-to-Propylene Reaction: A Mini Review

被引:72
作者
Galadima, Ahmad [1 ]
Muraza, Oki [1 ,2 ]
机构
[1] King Fahd Univ Petr & Minerals, Ctr Res Excellence Nanotechnol, Dhahran 31261, Saudi Arabia
[2] King Fahd Univ Petr & Minerals, Dept Chem Engn, Dhahran 31261, Saudi Arabia
关键词
CATALYZED METHYLATION REACTIONS; MESOPOROUS SSZ-13 ZEOLITE; REACTION-MECHANISM; MTO REACTION; MOLECULAR-SIEVES; PRODUCT DISTRIBUTION; OLEFIN CATALYSIS; VEGETABLE-OILS; LIGHT OLEFINS; SHAPE SELECTIVITY;
D O I
10.1021/acs.iecr.5b00338
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
The increase in shale gas supply stimulates the exploration of different conversion paths from natural gas to fuels and chemicals. Methanol is a natural gas derivative with a strategic role in the production of,fuels and chemicals. A. promising industrial option is the conversion of methanol feedstock into propylene under affordable and economical reaction Conditions. Although the methanol-to-hydrocarbon (MTH) reaction is a known technology for a few decades, key details related to catalyst development and overall experimental design must be fully explored. Therefore, the paper tailors recent updates on the progress made, especially on the key identified and prospective catalysts such as zeolites (i.e., silicoaluminates) and silicoaluminophosphates (SAPOs). This mini review also discusses the role of catalyst textural and acidity properties, reaction conditions, and associated reaction mechanisms.
引用
收藏
页码:4891 / 4905
页数:15
相关论文
共 171 条
[1]   Effects of static and stirring aging on physiochemical properties of SAPO-18 and its performance in MTO process [J].
Abdollahi, S. ;
Ghavipour, M. ;
Nazari, M. ;
Behbahani, R. M. ;
Moradi, G. R. .
JOURNAL OF NATURAL GAS SCIENCE AND ENGINEERING, 2015, 22 :245-251
[2]   Effect of crystallization time on properties and catalytic performance of nanostructured SAPO-34 molecular sieve synthesized at high temperatures for conversion of methanol to light olefins [J].
Aghaei, Erfan ;
Haghighi, Mohammad .
POWDER TECHNOLOGY, 2015, 269 :358-370
[3]   Microwave-assisted synthesis of plate-like SAPO-34 nanocrystals with increased catalyst lifetime in the methanol-to-olefin reaction [J].
Alvaro-Munoz, T. ;
Sastre, E. ;
Marquez-Alvarez, C. .
CATALYSIS SCIENCE & TECHNOLOGY, 2014, 4 (12) :4330-4339
[4]   Use of different templates on SAPO-34 synthesis: Effect on the acidity and catalytic activity in the MTO reaction [J].
Alvaro-Munoz, Teresa ;
Marquez-Alvarez, Carlos ;
Sastre, Enrique .
CATALYSIS TODAY, 2012, 179 (01) :27-34
[5]   Theoretical study of the methylbenzene side-chain hydrocarbon pool mechanism in methanol to olefin catalysis [J].
Arstad, B ;
Nicholas, JB ;
Haw, JF .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (09) :2991-3001
[6]   The reactivity of molecules trapped within the SAPO-34 cavities in the methanol-to-hydrocarbons reaction [J].
Arstad, B ;
Kolboe, S .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (33) :8137-8138
[7]  
Barger P., 2002, Zeolites for Cleaner Technologies, V3, P239, DOI DOI 10.1142/9781860949555_0012
[8]  
Barger P. T., 1992, US Pat., Patent No. [US5095163A, 5095163]
[9]   Prospects of biodiesel production from vegetables oils in India [J].
Barnwal, BK ;
Sharma, MP .
RENEWABLE & SUSTAINABLE ENERGY REVIEWS, 2005, 9 (04) :363-378
[10]   Conversion of methanol to hydrocarbons: the reactions of the heptamethylbenzenium cation over zeolite H-beta [J].
Bjorgen, M ;
Olsbye, U ;
Svelle, S ;
Kolboe, S .
CATALYSIS LETTERS, 2004, 93 (1-2) :37-40