Synthesis, structure and properties of ruthenium(II) complexes with quinolinedione derivatives as chelate ligands:: Crystal structure of [Ru(CO)2Cl2(6-methoxybenzo[g]quinoline-5,10-dione)]

被引：15
|
作者：
Prieto, Yolanda [1 ]
Munoz, Marcelo [1 ]
Arancibia, Veronica [1 ]
Valderrama, Mauricio [1 ]
Lahoz, Fernando J. [2 ]
Martin, M. Luisa [2 ]
机构：
[1] Pontificia Univ Catolica Chile, Fac Quim, Dept Quim Inorgan, Santiago 6094411, Chile
[2] Univ Zaragoza, Dept Quim Inorgan, Inst Ciencia Mat Aragon, CSIC, E-50009 Zaragoza, Spain
来源：
POLYHEDRON | 2007年 / 26卷 / 18期
关键词：
ruthenium; quinoline-5,10-dione complexes; dicarbonyl complexes; antitumor activity; crystal structure;
D O I：
10.1016/j.poly.2007.08.014
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The reaction of the dimer complex [{Ru(CO)(3)Cl-2}(2)] with the ligands 4,6-dichloroquinoline-5,8-dione and 6-methoxybenzo[g]quinoline-5, 10-dione in ethanol solution led to the neutral mononuclear complexes of general formula [Ru(CO)(2)Cl-2(kappa(2)-quinolinedione-N,O)]. The complexes were characterized by elemental analysis, IR and RMN spectroscopy, and the molecular structure of [Ru(CO)(2)Cl-2(6-methoxybenzo[g]quinoline-5,10-dione)] was determined by single-crystal X-ray diffraction. The redox chemistry of ligands and complexes was investigated by cyclic voltammetry, and their potential antitumor activity was also evaluated. (C) 2007 Elsevier Ltd. All rights reserved.
引用
收藏
页码：5527 / 5532
页数：6
相关论文
共 50 条
  • [41] Synthesis, Structure, and Reactivity of Ruthenium(0) Indane Complexes fac-[Ru(NCMe)3(CO)2(InX3)] (X = Cl, Br)
    Itazaki, Masumi
    Ito, Masaki
    Nakazawa, Hiroshi
    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2015, (12) : 2033 - 2036
  • [42] Cobalt(II), nickel(II), and copper(II) complexes of sulfanilamide derivatives: Synthesis, spectroscopic studies, and antibacterial activity, crystal structure of [Co(sulfacetamide)(2)(NCS)(2)]
    Blasco, F
    Perello, L
    Latorre, J
    Borras, J
    GarciaGranda, S
    JOURNAL OF INORGANIC BIOCHEMISTRY, 1996, 61 (02) : 143 - 154
  • [43] POLYAZA CAVITY-SHAPED MOLECULES .9. RUTHENIUM(II) COMPLEXES OF ANNELATED DERIVATIVES OF 2,2'-6,2''-TERPYRIDINE AND RELATED SYSTEMS - SYNTHESIS, PROPERTIES, AND STRUCTURE
    THUMMEL, RP
    JAHNG, Y
    INORGANIC CHEMISTRY, 1986, 25 (15) : 2527 - 2534
  • [44] Synthesis, structure and catalytic properties of CNN pincer palladium(II) and ruthenium(II) complexes with N-substituted-2-aminomethyl-6-phenylpyridines
    Wang, Tao
    Hao, Xin-Qi
    Zhang, Xiao-Xue
    Gong, Jun-Fang
    Song, Mao-Ping
    DALTON TRANSACTIONS, 2011, 40 (35) : 8964 - 8976
  • [45] The synthesis, crystal structure and photophysical properties of mononuclear platinum(II) 6-phenyl-[2,2′]bipyridinyl acetylide complexes
    Liu, Rui
    Chang, Jin
    Xiao, Qi
    Li, Yuhao
    Chen, Hongbin
    Zhu, Hongjun
    DYES AND PIGMENTS, 2011, 88 (01) : 88 - 94
  • [46] Binuclear ruthenium complexes of fluorous phosphine ligands: Synthesis, properties, and biphasic catalytic activity. Crystal structure of Ru(Ru(μ-O2CMe)(CO)2P(CH2CH2(CF2)5CF3)3]2
    Malosh, Thomas J.
    Wilson, Scott R.
    Shapley, John R.
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2009, 694 (20) : 3331 - 3337
  • [47] DITHIOPHOSPHINATE-BRIDGED RUTHENIUM(I) AND RUTHENIUM(II) COMPLEXES - STRUCTURE OF [RU2(CO)4(MU-S2PME2)2(PPH3)2].1/2CH2CL2
    HILTS, RW
    COWIE, M
    INORGANIC CHEMISTRY, 1990, 29 (18) : 3349 - 3354
  • [48] Synthesis, crystal structure, and electronic structure of a copper(II) chloride complex with 9(E)-phenanthrene-9,10-dione[(1Z)-3,3-dimethyl-3,4-dihydroisoquinolin-1(2H)-ylidene]hydrazone [Cu2(L-H)2Cl2]
    V. V. Davydov
    V. I. Sokol
    N. V. Rychagina
    R. V. Linko
    M. A. Ryabov
    P. V. Strashnov
    V. S. Sergienko
    Russian Journal of Inorganic Chemistry, 2014, 59 : 927 - 934
  • [49] Synthesis, crystal structure, and electronic structure of a copper(II) chloride complex with 9(E)-phenanthrene-9,10-dione[(1Z)-3,3-dimethyl-3,4-dihydroisoquinolin-1(2H)-ylidene]hydrazone [Cu2(L-H)2Cl2]
    Davydov, V. V.
    Sokol, V. I.
    Rychagina, N. V.
    Linko, R. V.
    Ryabov, M. A.
    Strashnov, P. V.
    Sergienko, V. S.
    RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2014, 59 (09) : 927 - 934
  • [50] Synthesis and properties of the dichloro[tetramethyl(trifluoromethyl)cyclopentadienyl]ruthenium dimer:: X-ray structure of [M2(η5-C5Me4CF3)2Cl2(μ-Cl)2] (M = Ru, Rh)
    Gusev, OV
    Ievlev, MA
    Lyssenko, KA
    Petrovskii, PV
    Ustynyuk, NA
    Maitlis, PM
    INORGANICA CHIMICA ACTA, 1998, 280 (1-2) : 249 - 256
12345