Tunable smart surface of gold nanoparticles achieved by light-controlled molecular recognition effection

被引：31

作者：

Luo, Chunhua ^{[2
,3
]}

Zuo, Fang ^{[2
,3
]}

Zheng, Zhaohui ^{[1
]}

Cheng, Xu ^{[1
]}

Ding, Xiaobin ^{[1
]}

Peng, Yuxing ^{[1
]}

机构：

[1] Chinese Acad Sci, Chengdu Inst Organ Chem, Chengdu 610041, Peoples R China

[2] Chinese Acad Sci, Grad Sch, Beijing 100081, Peoples R China

[3] Chinese Acad Sci, Chengdu Inst Organ Chem, Chengdu 610041, Peoples R China

来源：

MACROMOLECULAR RAPID COMMUNICATIONS | 2008年 / 29卷 / 02期

关键词：

azo polymers; gold nanoparticles; molecular recognition; smart surface;

D O I：

10.1002/marc.200700555

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Thermosensitive poly(N-isopropylacrylamide) (PNIPAm)-coated gold nanoparticles (AuNPs) were prepared by self-assembly of the azobenzene-terminated PNIPAm on the surface of the alpha-cyclodextrin (alpha-CD)-capped AuNPs via the host-guest molecular recognition between a-CD and azobenzene. Reversible attachment-detachment of azobenzene-terminated PNIPAm on the surface of alpha-CD-capped AuNPs was achieved when subjected to visible and UV light irradiation alternately, which endowed thermosensitive AuNPs with tunable smart properties.

引用

页码：149 / 154

页数：6

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