Nanoarchitectonics at surfaces using multifunctional initiators of surface-initiated radical polymerization for fabrication of the nanocomposites

被引：29
作者：
Donchak, Volodymyr [1 ]
Stetsyshyn, Yurij [1 ]
Bratychak, Michael [2 ]
Broza, Georg [3 ]
Harhay, Khrystyna [1 ]
Stepina, Nataliia [1 ]
Kostenko, Mariia [1 ]
Voronov, Stanislav [1 ]
机构：
[1] Lviv Polytech Natl Univ, Dept Organ Chem, St Georges Sq 2, UA-79013 Lvov, Ukraine
[2] Lviv Polytech Natl Univ, Dept Chem Technol Oil & Gas Proc, St Georges Sq 2, UA-79013 Lvov, Ukraine
[3] Hamburg Univ Technol, Inst Polymer Composites, Denickestr 15, D-21073 Hamburg, Germany
来源：
APPLIED SURFACE SCIENCE ADVANCES | 2021年 / 5卷
关键词：
Nanoarchitectonics; Nanocomposites; MWCNTs; Multifunctional initiators of surface-initiated radical polymerization; Surface modification; WALLED CARBON NANOTUBES; OF-THE-ART; FUNCTIONALIZATION; COMPOSITES; POLYSTYRENE; DISPERSION; PEROXIDES; POLYMERS; CELLS;
D O I：
10.1016/j.apsadv.2021.100104
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
In this work, the nanoarchitectonics approach to synthesize a new functional material with certain configurations and hierarchical motifs of the multifunctional initiators of surface-initiated radical polymerization (MPIs) on surface of multi-wall carbon nanotubes (MWCNTs) was realized. The presence of covalently-linked MPIs on the surfaces of amine functionalized MWCNTs was confirmed by Raman spectroscopy and thermal analysis. Nanocomposites of polybutylene terephthalate - poly(tetramethylene oxide) - (PBT/PTMO) with modified nanotubes show higher values of Young's modulus, elongation at break, and crystallization temperature in comparison to nonmodified ones.
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页数：7
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共 72 条
  • [1] Synthesis of Polyethylene-Grafted Multiwalled Carbon Nanotubes via a Peroxide-Initiating Radical Coupling Reaction and by Using Well-Defined TEMPO and Thiol End-Functionalized Polyethylenes
    Akbar, Sohaib
    Beyou, Emmanuel
    Chaumont, Philippe
    Mazzolini, Jerome
    Espinosa, Edgar
    D'Agosto, Franck
    Boisson, Christophe
    [J]. JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2011, 49 (04) : 957 - 965
  • [2] Effect of a Nitroxyle-Based Radical Scavenger on Nanotube Functionalisation with Pentadecane: A Model Compound Study for Polyethylene Grafting onto MWCNTs
    Akbar, Sohaib
    Beyou, Emmanuel
    Chaumont, Philippe
    Melis, Flavien
    [J]. MACROMOLECULAR CHEMISTRY AND PHYSICS, 2010, 211 (22) : 2396 - 2406
  • [3] Carbon nanotube polymer composites
    Andrews, R
    Weisenberger, MC
    [J]. CURRENT OPINION IN SOLID STATE & MATERIALS SCIENCE, 2004, 8 (01) : 31 - 37
  • [4] The Way to Nanoarchitectonics and the Way of Nanoarchitectonics
    Aono, Masakazu
    Ariga, Katsuhiko
    [J]. ADVANCED MATERIALS, 2016, 28 (06) : 989 - 992
  • [5] Atomic and Organic Nanoarchitectonics
    Ariga, Katsuhiko
    [J]. TRENDS IN CHEMISTRY, 2020, 2 (09): : 779 - 782
  • [6] Intelligent Nanoarchitectonics for Self-Assembling Systems
    Ariga, Katsuhiko
    Shrestha, Lok Kumar
    [J]. ADVANCED INTELLIGENT SYSTEMS, 2020, 2 (04)
  • [7] Layer-by-Layer Assembly: Recent Progress from Layered Assemblies to Layered Nanoarchitectonics
    Ariga, Katsuhiko
    Ahn, Eungjin
    Park, Minju
    Kim, Byeong-Su
    [J]. CHEMISTRY-AN ASIAN JOURNAL, 2019, 14 (15) : 2553 - 2566
  • [8] Nanoarchitectonics
    Ariga, Katsuhiko
    Aono, Masakazu
    [J]. JAPANESE JOURNAL OF APPLIED PHYSICS, 2016, 55 (11)
  • [9] Highly functionalized carbon nanotubes using in situ generated diazonium compounds
    Bahr, JL
    Tour, JM
    [J]. CHEMISTRY OF MATERIALS, 2001, 13 (11) : 3823 - +
  • [10] Polymer Brushes via Surface-Initiated Controlled Radical Polymerization: Synthesis, Characterization, Properties, and Applications
    Barbey, Raphael
    Lavanant, Laurent
    Paripovic, Dusko
    Schuewer, Nicolas
    Sugnaux, Caroline
    Tugulu, Stefano
    Klok, Harm-Anton
    [J]. CHEMICAL REVIEWS, 2009, 109 (11) : 5437 - 5527
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