Solubility of chlorobutane, ethyl methacrylate and trifluoroethyl acrylate in supercritical carbon dioxide

被引：34

作者：

Wang, B ^{[1
]}

He, J ^{[1
]}

Sun, DH ^{[1
]}

Zhang, R ^{[1
]}

Han, BX ^{[1
]}

机构：

[1] Chinese Acad Sci, Inst Chem, Ctr Mol Sci, Beijing 100080, Peoples R China

来源：

FLUID PHASE EQUILIBRIA | 2006年 / 239卷 / 01期

关键词：

solubility of solute; SCCO2; polar substitute effect; the influence of density;

D O I：

10.1016/j.fluid.2005.10.023

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

In this work, the solubility of chlorobutane, ethyl methacrylate and trifluoroethyl acrylate in supercritical carbon dioxide (SCCO2) was determined. The solubility of hexane, styrene and chlorobenzene was also measured for comparison. The effect of the polar substitute on the solubility of different kind of compound in SC CO2 was discussed. The dependence of the solubility of the solute on the density of the binary system was also investigated and a proximate linear relationship existed between this solubility and density. (c) 2005 Elsevier B.V. All rights reserved.

引用

页码：63 / 68

页数：6

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