Photocatalytic degradation of methylene blue using monometallic and bimetallic Bi-Fe doped TiO2

被引:56
作者
Mishra, Saurav [1 ]
Chakinala, Nandana [2 ]
Chakinala, Anand G. [2 ]
Surolia, Praveen K. [1 ]
机构
[1] Manipal Univ Jaipur, Dept Chem, Solar Energy Convers & Nanomat Lab, Jaipur 303007, Rajasthan, India
[2] Manipal Univ Jaipur, Dept Chem Engn, Chem React Engn Lab, Jaipur 303007, Rajasthan, India
关键词
Photocatalytic degradation; M-dopedTiO(2) (M-Bi-Fe); Methylene blue; Wet impregnation; ORGANIC CONTAMINANTS; DYES; PHOTOLUMINESCENCE; MINERALIZATION; NANOPARTICLES;
D O I
10.1016/j.catcom.2022.106518
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
This work reports synthesis and characterization of mono and bimetal doped TiO2-based photocatalyts using Bi and Fe metals prepared via wet impregnation method. Photocatalytic performances of the synthesized catalysts were tested for the degradation of methylene blue. Results revealed that 1%Bi/TiO2 (w/w) exhibited best photocatalytic performance and achieved 80% degradation of 50 ppm MB solution within two hours. The monometallic doping showed better performance than the bimetallic doping of Bi and Fe. This diminished performance with co-doping was due to the agglomeration effect which accelerates recombination of electrons and holes. First order-kinetic model was used for the study of degradation.
引用
收藏
页数:5
相关论文
共 35 条
[1]   Synthesis, characterization and application of bismuth and boron Co-doped TiO2: A visible light active photocatalyst [J].
Bagwasi, Segomotso ;
Tian, Baozhu ;
Zhang, Jinlong ;
Nasir, Muhammad .
CHEMICAL ENGINEERING JOURNAL, 2013, 217 :108-118
[2]   Structural and textural characterization of AlPO4-B2O3 and Al2O3-B2O3 (5-30 wt% B2O3) systems obtained by boric acid impregnation [J].
Bautista, FM ;
Campelo, JM ;
Garcia, A ;
Luna, D ;
Marinas, JM ;
Moreno, MC ;
Romero, AA ;
Navio, JA ;
Macias, M .
JOURNAL OF CATALYSIS, 1998, 173 (02) :333-344
[3]   Photoluminescence and Photocatalytic Properties of Ag3PO4 Microcrystals: An Experimental and Theoretical Investigation [J].
Botelho, Gleice ;
Andres, Juan ;
Gracia, Lourdes ;
Matos, Leandro S. ;
Longo, Elson .
CHEMPLUSCHEM, 2016, 81 (02) :202-212
[4]   Highly efficient bi-metallic bismuth-silver doped TiO2 photocatalyst for dye degradation [J].
Chakinala, Nandana ;
Gogate, Parag Ratnakar ;
Chakinala, Anand Gupta .
KOREAN JOURNAL OF CHEMICAL ENGINEERING, 2021, 38 (12) :2468-2478
[5]   Photocatalytic degradation of organic pollutants using TiO2-based photocatalysts: A review [J].
Chen, Dongjie ;
Cheng, Yanling ;
Zhou, Nan ;
Chen, Paul ;
Wang, Yunpu ;
Li, Kun ;
Huo, Shuhao ;
Cheng, Pengfei ;
Peng, Peng ;
Zhang, Renchuang ;
Wang, Lu ;
Liu, Hui ;
Liu, Yuhuan ;
Ruan, Roger .
JOURNAL OF CLEANER PRODUCTION, 2020, 268
[6]   In-situ synthesis of facet-dependent BiVO4/Ag3PO4/PANI photocatalyst with enhanced visible-light-induced photocatalytic degradation performance: Synergism of interfacial coupling and hole-transfer [J].
Chen, Sha ;
Huang, Danlian ;
Zeng, Guangming ;
Xue, Wenjing ;
Lei, Lei ;
Xu, Piao ;
Deng, Rui ;
Li, Jing ;
Cheng, Min .
CHEMICAL ENGINEERING JOURNAL, 2020, 382
[7]   Visible-light activation of TiO2 photocatalysts: Advances in theory and experiments [J].
Etacheri, Vinodkumar ;
Di Valentin, Cristiana ;
Schneider, Jenny ;
Bahnemann, Detlef ;
Pillai, Suresh C. .
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY C-PHOTOCHEMISTRY REVIEWS, 2015, 25 :1-29
[8]   Photoluminescence, TGA/DSC and photocatalytic activity studies of Dy3+ doped SrY2O4 nanophosphors [J].
Ghorpade, Santosh P. ;
Kottam, Nagaraju ;
Melavanki, Raveendra ;
Patil, N. R. .
RSC ADVANCES, 2020, 10 (36) :21049-21056
[9]   Solar Light-Irradiated Photocatalytic Degradation of Model Dyes and Industrial Dyes by a Magnetic CoFe2O4-gC3N4 S-Scheme Heterojunction Photocatalyst [J].
Gogoi, Debika ;
Makkar, Priyanka ;
Ghosh, Narendra Nath .
ACS OMEGA, 2021, 6 (07) :4831-4841
[10]   Metal-organic framework derived multi-functionalized and co-doped TiO2/C nanocomposites for excellent visible-light photocatalysis [J].
Hussain, Mian Zahid ;
Yang, Zhuxian ;
Khalil, Ahmed M. E. ;
Hussain, Shahzad ;
Awan, Saif Ullah ;
Jia, Quanli ;
Fischer, Roland A. ;
Zhu, Yanqiu ;
Xia, Yongde .
JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY, 2022, 101 :49-59