Electrosynthesis of Chirality Conducting Poly[N-(9-fluorenylmethoxycarbonyl)-L-phenylalanine] with Good Blue Light-Emitting Properties

被引：1

作者：

Lai Cunyuan ^{[1
]}

Guo Wenjuan ^{[1
]}

Tang Xinde ^{[2
]}

Pei Meishan ^{[1
]}

机构：

[1] Univ Jinan, Sch Chem & Chem Engn, Jinan 250022, Shandong, Peoples R China

[2] Shandong Jiaotong Univ, Inst New Mat, Jinan 250023, Shandong, Peoples R China

来源：

CHINESE JOURNAL OF CHEMISTRY | 2012年 / 30卷 / 03期

基金：

中国国家自然科学基金;

关键词：

chirality; poly[N-(9-fluorenylmethoxycarbonyl)-L-phenylalanine; good solubility; blue-light emitter; TRIFLUORIDE DIETHYL ETHERATE; ELECTROCHEMICAL POLYMERIZATION; POLYFLUORENE DERIVATIVES; POLYPYRROLE; POLYMERS; FILMS; POLYTHIOPHENES; EFFICIENT; DIODES;

D O I：

10.1002/cjoc.201100087

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Poly[N-(9-fluorenylmethoxycarbonyl)-L-phenylalanine] (PN9FPA) films with good fluorescence properties and chirality were prepared electrochemically by direct anodic oxidation of N-(9-fluorenylmethoxycarbonyl)-L-phenylalanine (N9FPA) in boron trifluoride diethyletherate (BFEE). Fourier transform infrared spectroscopy measurement showed that the polymerization of N9FPA occurred mainly at the C(2) and C(7) positions. The fluorescence spectra indicated that PN9FPA films were blue-light emitters. In addition, the structures and properties of the monomer and the polymers were characterized and evaluated with CV, UV, TGA and SEM.

引用

页码：507 / 511

页数：5

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