Nickel-catalyzed Arbuzov reactions of aryl triflates with triethyl phosphite

被引：62
作者：
Yang, Guoqiang [1 ]
Shen, Chaoren [1 ]
Zhang, Liang [1 ]
Zhang, Wanbin [1 ]
机构：
[1] Shanghai Jiao Tong Univ, Sch Chem & Chem Engn, Shanghai 200240, Peoples R China
来源：
TETRAHEDRON LETTERS | 2011年 / 52卷 / 39期
基金：
中国国家自然科学基金;
关键词：
Arbuzov reaction; Nickel; Aryl triflate; Triethyl phosphite; Alkali metal halide; H-PHOSPHONATE DIESTERS; CROSS-COUPLING REACTIONS; CARBON BOND FORMATION; ASYMMETRIC HYDROGENATION; REDUCTIVE ELIMINATION; RECEPTOR ANTAGONISTS; EFFICIENT LIGAND; VINYL HALIDES; P-ARYLATION; ACID;
D O I：
10.1016/j.tetlet.2011.07.077
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
An efficient method was developed for the nickel-catalyzed phosphonylation of aryl triflates with triethyl phosphite, in which KBr as an additive promoted the S(N)2 catalytic step. To the best of our knowledge, this is the first example of nickel-catalyzed Arbuzov reactions of aryl triflates. Most of the substrates showed good reactivity under this catalytic system. (C) 2011 Elsevier Ltd. All rights reserved.
引用
收藏
页码：5032 / 5035
页数：4
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