Design of Novel Brush-Shaped π-Conjugated Polymers Based on the Controlled Synthesis of Poly(vinyl ether)s with a Terminal Ethynylbenzene Moiety

被引：0

作者：

Moroyanagi, Jin ^{[1
]}

Ishikawa, Taketo ^{[1
]}

Kurata, Akihiro ^{[1
]}

Minoda, Masahiko ^{[1
]}

机构：

[1] Kyoto Inst Technol, Grad Sch Sci & Technol, Sakyo Ku, Kyoto 6068585, Japan

来源：

KOBUNSHI RONBUNSHU | 2015年 / 72卷 / 05期

关键词：

pi-Conjugated Polymer; Graft Polymer; Macromonomer with a Diethynylbenzene Moiety; Living Cationic Polymerization; Vinyl Ether; POLYMERIZATION; COPOLYMERS;

D O I：

10.1295/koron.2014-0094

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Various pi-conjugated polymers have been synthesized for advanced materials possessing electrically-conductive and photoluminescence properties. In this study, for the synthesis of novel pi-conjugated polymers grafted with poly(vinyl ether) pendants by the "grafting through" methodology, a poly(vinyl ether)-based macromonomer bearing a diethynylbenzene group at the terminus (DE-PIBVE) was synthesized. First, the macromonomer was synthesized by living cationic polymerization of isobutyl vinyl ether using a diethynylbenzene-appended initiator (TMS-DEVE-TFA) in conjunction with EtAlCl2 and dioxane, followed by deprotection with TBAF. Then, oxidative coupling reaction of the terminal diethynylbenzene group of DE-PIBVE afforded the target brush-shaped polymer having a poly(phenylene butadiynylene) backbone [Poly(DE-PIBVE)].

引用

页码：318 / 323

页数：6

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