Sodium storage and transport properties in pyrolysis synthesized MoSe2 nanoplates for high performance sodium-ion batteries

被引:164
作者
Wang, Hui [1 ]
Lan, Xinzheng [1 ]
Jiang, Danlu [1 ]
Zhang, Yan [1 ]
Zhong, Honghai [1 ]
Zhang, Zhongping [1 ,2 ]
Jiang, Yang [1 ]
机构
[1] Hefei Univ Technol, Sch Mat Sci & Engn, Hefei 230009, Anhui, Peoples R China
[2] Chaohu Univ, Sch Chem Chem Engn & Life Sci, Hefei 238000, Peoples R China
基金
高等学校博士学科点专项科研基金; 国家高技术研究发展计划(863计划); 中国国家自然科学基金;
关键词
Sodium-ion batteries; MoSe2; nanoplates; First-principles calculation; Anode materials; Ion diffusion barrier; ELECTROCHEMICAL PROPERTIES; ELECTRODE MATERIALS; ASSISTED SYNTHESIS; ENERGY-STORAGE; ANODE MATERIAL; LITHIUM; NANOCOMPOSITE; MECHANISMS; CHALLENGES; CATHODES;
D O I
10.1016/j.jpowsour.2015.02.096
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The development of novel sodium-ion batteries has been hindered by the lack of ideal anode materials. Herein, we report both experimental and theoretical assessment of layered MoSe2 nanoplates as the anode materials. The MoSe2 nanoplates are successfully synthesized by a facile thermal-decomposition process. As the anode, the MoSe2 nanoplates are capable of delivering the initial discharge and charge capacities of 513 and 440 mAh g(-1) at the current of 0.1C in a voltage of 0.1-3 V, respectively. The analysis of Ex-situ XRD patterns reveals that there is no slippage between layers and the change of coordination of molybdenum when the MoSe2 electrode is discharged to 0.6 V and conversion reactions during the following discharge/charge process are also demonstrated. In addition, the electronic structure, Na ions transport and conductivity are investigated by first-principles calculation. A quasi-2D energy favorable trajectory is proposed to illustrate the sodium ion vacancy-hopping migration mechanism form octahedron to tetrahedron in MoSe2 lattice. The results suggest great potential of MoSe2 as an anode material for Na ion batteries. (C) 2015 Elsevier B.V. All rights reserved.
引用
收藏
页码:187 / 194
页数:8
相关论文
共 48 条
[1]   Two-Dimensional Molybdenum Trioxide and Dichalcogenides [J].
Balendhran, Sivacarendran ;
Walia, Sumeet ;
Nili, Hussein ;
Ou, Jian Zhen ;
Zhuiykov, Serge ;
Kaner, Richard B. ;
Sriram, Sharath ;
Bhaskaran, Madhu ;
Kalantar-zadeh, Kourosh .
ADVANCED FUNCTIONAL MATERIALS, 2013, 23 (32) :3952-3970
[2]   PROJECTOR AUGMENTED-WAVE METHOD [J].
BLOCHL, PE .
PHYSICAL REVIEW B, 1994, 50 (24) :17953-17979
[3]   Beyond Intercalation-Based Li-Ion Batteries: The State of the Art and Challenges of Electrode Materials Reacting Through Conversion Reactions [J].
Cabana, Jordi ;
Monconduit, Laure ;
Larcher, Dominique ;
Rosa Palacin, M. .
ADVANCED MATERIALS, 2010, 22 (35) :E170-E192
[4]   L-Cysteine-Assisted Synthesis of Layered MoS2/Graphene Composites with Excellent Electrochemical Performances for Lithium Ion Batteries [J].
Chang, Kun ;
Chen, Weixiang .
ACS NANO, 2011, 5 (06) :4720-4728
[5]   Functional Materials for Rechargeable Batteries [J].
Cheng, Fangyi ;
Liang, Jing ;
Tao, Zhanliang ;
Chen, Jun .
ADVANCED MATERIALS, 2011, 23 (15) :1695-1715
[6]   Electrochemical deposition of porous Co3O4 nanostructured thin film for lithium-ion battery [J].
Chou, Shu-Lei ;
Wang, Jia-Zhao ;
Liu, Hua-Kun ;
Dou, Shi-Xue .
JOURNAL OF POWER SOURCES, 2008, 182 (01) :359-364
[7]   ELECTRONIC-STRUCTURE OF MOSE2, MOS2, AND WSE2 .1. BAND-STRUCTURE CALCULATIONS AND PHOTOELECTRON-SPECTROSCOPY [J].
COEHOORN, R ;
HAAS, C ;
DIJKSTRA, J ;
FLIPSE, CJF ;
DEGROOT, RA ;
WOLD, A .
PHYSICAL REVIEW B, 1987, 35 (12) :6195-6202
[8]   Layered Na0.71CoO2: a powerful candidate for viable and high performance Na-batteries [J].
D'Arienzo, Massimiliano ;
Ruffo, Riccardo ;
Scotti, Roberto ;
Morazzoni, Franca ;
Maria, Claudio Maria ;
Polizzi, Stefano .
PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2012, 14 (17) :5945-5952
[9]   Better Cycling Performances of Bulk Sb in Na-Ion Batteries Compared to Li-Ion Systems: An Unexpected Electrochemical Mechanism [J].
Darwiche, Ali ;
Marino, Cyril ;
Sougrati, Moulay T. ;
Fraisse, Bernard ;
Stievano, Lorenzo ;
Monconduit, Laure .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2012, 134 (51) :20805-20811
[10]   ORTHORHOMBIC NAXMNO2 AS A CATHODE MATERIAL FOR SECONDARY SODIUM AND LITHIUM POLYMER BATTERIES [J].
DOEFF, MM ;
PENG, MY ;
MA, YP ;
DEJONGHE, LC .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1994, 141 (11) :L145-L147