Hard carbons for sodium-ion batteries and beyond

被引:180
作者
Xie, Fei [1 ,2 ,3 ]
Xu, Zhen [2 ]
Guo, Zhenyu [2 ]
Titirici, Maria-Magdalena [2 ]
机构
[1] Chinese Acad Sci, Inst Phys, Key Lab Renewable Energy, Beijing Key Lab New Energy Mat & Devices, Beijing 100190, Peoples R China
[2] Imperial Coll London, Dept Chem Engn, London SW7 2AZ, England
[3] Queen Mary Univ London, Sch Phys & Astron, London E1 4NS, England
来源
PROGRESS IN ENERGY | 2020年 / 2卷 / 04期
基金
英国工程与自然科学研究理事会;
关键词
Sodium-ion batteries; hard carbons; anodes; energy storage; NITROGEN-DOPED CARBON; HIGH-CAPACITY ANODE; POROUS CARBON; LOW-COST; ENERGY-STORAGE; LITHIUM-ION; ELECTROCHEMICAL PERFORMANCE; MECHANISTIC INSIGHTS; NEGATIVE ELECTRODES; ACTIVATED CARBON;
D O I
10.1088/2516-1083/aba5f5
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
Sodium-ion batteries (SIBs) are one of the most promising alternatives to lithium-ion batteries (LIBs), due to the much more abundant resources of Na compared with Li in the world. Developing SIB technology to satisfy the increased demand for energy storageis therefore a significant task. However, one of the biggest bottlenecks is the design of high-performance and low-cost anode materials, since the graphite anode in commercial LIBs is not suitable for SIBs due to thermal dynamic issues. Hard carbon materials have been regarded as having the greatest potential as anodes in commercial SIBs owing to their excellent cost-effectiveness, but their relatively limited performance compared to the graphite in LIBs as well as the dimness of the sodium storage mechanisms still need further investigation. In this review, we summarize the progress of recent research into hard carbons for SIB applications, including the fundamentals of SIBs, sodium storage mechanisms, structures and the electrochemical performances of different types of hard carbons in SIBs and other types of sodium-based energy storage as well as the main challenges in this field. We aim to provide a general insight into hard carbons and their applications in SIBs, opening up future perspectives and possible research directions.
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页数:30
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