Amide-aromatic hydrogen-bonds in host-guest recognition

被引：60

作者：

Adams, H ^{[1
]}

Carver, FJ ^{[1
]}

Hunter, CA ^{[1
]}

Osborne, NJ ^{[1
]}

机构：

[1] UNIV SHEFFIELD,DEPT CHEM,KREBS INST BIOMOL SCI,SHEFFIELD S3 7HF,S YORKSHIRE,ENGLAND

来源：

CHEMICAL COMMUNICATIONS | 1996年 / 22期

关键词：

D O I：

10.1039/cc9960002529

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Complexes between a macrocylic tetraamide and dicarbonyl substrates have been used to investigate the interaction of functional groups with the face of an aromatic ring; amide NH groups directed towards the pi-electron density an the face of the ring produce a substantial increase in binding energy in chloroform which suggests that pi-facial H-bonds can be important in molecular recognition.

引用

页码：2529 / 2530

页数：2

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