Fire retardancy of polypropylene/flax blends

被引:175
作者
Schartel, B
Braun, U
Schwarz, U
Reinemann, S
机构
[1] Fed Inst Mat Res & Testing, D-12205 Berlin, Germany
[2] Ostthuring Mat Prufgesell Text & Kunststoffe MbH, D-07407 Rudolstadt, Germany
[3] Thuring Inst Text & Kunststoff Forsch EV, D-07407 Rudolstadt, Germany
关键词
biocomposites; flame retardancy; flax;
D O I
10.1016/S0032-3861(03)00692-X
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
A comprehensive characterization of the thermal and the fire behaviour is presented for polypropylene (PP) flax compounds containing ammonium polyphosphate (APP) and expandable graphite as fire retardants. Thermogravimetry coupled with an evolved gas analysis (TG-FTIR) was performed to ensure a significant thermal analysis. The fire response under forced flaming conditions was studied using a cone calorimeter. The external heat flux was varied between 30 and 70 kW m(-2) so that the results could be evaluated for different fire scenarios and tests. Different flammability tests (UL 94, limiting oxygen index, glow wire test, GMI 60261) were performed and the results compared with the cone calorimeter data. The different char forming mechanisms are described and the resulting fire retardancy is classified. The successful and ecological friendly fire retardancy is a technological breakthrough for PP/flax biocomposites. (C) 2003 Elsevier Ltd. All rights reserved.
引用
收藏
页码:6241 / 6250
页数:10
相关论文
共 46 条
  • [1] Babrauskas V., 1992, Heat release in fires, P207
  • [2] CARBONIZATION MECHANISMS RESULTING FROM INTUMESCENCE .2. ASSOCIATION WITH AN ETHYLENE TERPOLYMER AND THE AMMONIUM POLYPHOSPHATE PENTAERYTHRITOL FIRE-RETARDANT SYSTEM
    BOURBIGOT, S
    LEBRAS, M
    DELOBEL, R
    BREANT, P
    TREMILLON, JM
    [J]. CARBON, 1995, 33 (03) : 283 - 294
  • [3] Thermal behaviour of ethylene-propylene rubber/polyurethane/ammonium polyphosphate intumescent formulations - a kinetic study
    Bugajny, M
    Le Bras, M
    Bourbigot, S
    Delobel, R
    [J]. POLYMER DEGRADATION AND STABILITY, 1999, 64 (01) : 157 - 163
  • [4] CAMINO C, 2000, FIRE RETARDANCY POLY, P217
  • [5] STUDY OF THE MECHANISM OF INTUMESCENCE IN FIRE RETARDANT POLYMERS .2. MECHANISM OF ACTION IN POLYPROPYLENE-AMMONIUM POLYPHOSPHATE PENTAERYTHRITOL MIXTURES
    CAMINO, G
    COSTA, L
    TROSSARELLI, L
    [J]. POLYMER DEGRADATION AND STABILITY, 1984, 7 (01) : 25 - 31
  • [6] Mechanism of fire retardancy of polyurethanes using ammonium polyphosphate
    Duquesne, S
    Le Bras, M
    Bourbigot, S
    Delobel, R
    Camino, G
    Eling, B
    Lindsay, C
    Roels, T
    Vezin, H
    [J]. JOURNAL OF APPLIED POLYMER SCIENCE, 2001, 82 (13) : 3262 - 3274
  • [7] Analysis of fire gases released from polyurethane and fire-retarded polyurethane coatings
    Duquesne, S
    Le Bras, M
    Bourbigot, S
    Delobel, R
    Poutch, F
    Camino, G
    Eling, B
    Lindsay, C
    Roels, T
    [J]. JOURNAL OF FIRE SCIENCES, 2000, 18 (06) : 456 - 482
  • [8] Elias H.-G., 2003, MAKROMOLEKULE, V4
  • [9] Mechanical properties of natural-fibre-mat-reinforced thermoplastics based on flax fibres and polypropylene
    Garkhail, SK
    Heijenrath, RWH
    Peijs, T
    [J]. APPLIED COMPOSITE MATERIALS, 2000, 7 (5-6) : 351 - 372
  • [10] Green J., 2000, FIRE RETARDANCY POLY, P147