Synthesis of Bottlebrush Polymers by Ring-Opening Metathesis Polymerization

被引：8
|
作者：
Chen, Kerui [1 ]
Hu, Xin [2 ]
Qiu, Jiangkai [1 ]
Zhu, Ning [1 ]
Guo, Kai [1 ]
机构：
[1] Nanjing Tech Univ, Coll Biotechnol & Pharmaceut Engn, State Key Lab Mat Oriented Chem Engn, Nanjing 211800, Peoples R China
[2] Nanjing Tech Univ, Coll Mat Sci & Engn, Nanjing 211800, Peoples R China
来源：
PROGRESS IN CHEMISTRY | 2020年 / 32卷 / 01期
基金：
中国国家自然科学基金;
关键词：
bottlebrush polymers; ring-opening metathesis polymerization; copolymers; BRUSH BLOCK-COPOLYMERS; PHOTONIC CRYSTALS; ANIONIC-POLYMERIZATION; RUTHENIUM CATALYSTS; MOLECULAR BRUSHES; TANDEM SYNTHESIS; TRANSFER-TO; ROMP; CORE; VISUALIZATION;
D O I：
10.7536/PC190607
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Bottlebrush polymers are a class of comb polymers that have the unique side chain structures and properties. Functional bottlebrush polymers have found broad applications in photonic crystals , surfactants , pharmaceutical carriers , antifouling coatings and smart materials. The synthetic strategies to bottlebrush polymers by ring-opening metathesis polymerization (ROMP) exhibit various advantages , such as simple synthesis steps , high polymer graft density and uniform side chain composition. Well control of polymer composition, molecular weight and molecular weight dispersity could be achieved by ROMP. This review summarizes the synthesis of homo, block, Janus, core-shell bottlebrush copolymers via ROMP. Moreover, the advances in finely controlling the bottlebrush polymer architecture are discussed.
引用
收藏
页码：93 / 102
页数：10
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