Volumetric Properties of Amino Acids in Aqueous Solutions of Glucosamine Hydrochloride at T=293.15-313.15 K

被引：2

作者：

Li, Dan ^{[1
]}

Guo, Meng ^{[1
]}

Kong, Xiangjun ^{[1
]}

Dai, Guangjian ^{[1
]}

Lin, Shutong ^{[1
]}

机构：

[1] Weifang Univ, Dept Chem & Chem Engn, Weifang 261061, Shandong, Peoples R China

来源：

RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A | 2019年 / 93卷 / 13期

关键词：

glucosamine; amino acid; density; apparent molar volume; hydration number; PARTIAL MOLAR VOLUMES; HYDROXYPROPYL-BETA-CYCLODEXTRIN; L-ALANINE; GLYCINE; WATER; MECHANISMS; SERINE; NACL;

D O I：

10.1134/S0036024419130132

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The densities (rho) of glycine, L-alanine, L-serine, and L-threonine solutions in 0.05, 0.10, 0.15, 0.20, and 0.30 mol kg(-1) aqueous solutions of D-glucosamine hydrochloride have been measured at T = 293.15, 298.15, 303.15, 308.15, and 313.15 K. The apparent molar volumes (V-phi), limiting partial molar volumes (V-phi(0)) of the amino acids have been calculated from the density data. Transfer partial molar volumes (Delta V-tr(phi)0) and hydration numbers from water to the aqueous solutions of D-glucosamine hydrochloride were also obtained. These parameters of volumetric properties can help to understand the mixing effects and interactions between amino acids and D-glucosamine hydrochloride aqueous solution.

引用

页码：2635 / 2644

页数：10

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