Self-assembly of conducting cocrystals via iodine ... π(Cp) interactions

被引：21
|
作者：
Torubaev, Yury V. [1 ]
Lyssenko, Konstantin A. [2 ]
Barzilovich, Petro Y. [3 ]
Saratov, George A. [3 ]
Shaikh, Mobin M. [4 ]
Singh, Ajeet [4 ]
Mathur, Pradeep [4 ]
机构：
[1] Russian Acad Sci, NS Kurnakov Inst Gen & Inorgan Chem, Moscow, Russia
[2] Russian Acad Sci, AN Nesmeyanov Inst Organoelement Cpds, Moscow, Russia
[3] Moscow Inst Phys & Technol, Dolgoprudnyi, Moscow Region, Russia
[4] Indian Inst Technol Indore, Sch Basic Sci, Indore, Madhya Pradesh, India
来源：
CRYSTENGCOMM | 2017年 / 19卷 / 34期
基金：
俄罗斯基础研究基金会;
关键词：
HALOGEN-BOND DONORS; SUPRAMOLECULAR MATERIALS; M-X; COMPLEXES; CHEMISTRY; HYDROGEN; FEATURES;
D O I：
10.1039/c7ce00857k
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Conducting crystals of alternating ferrocene and diiodoacetylene units assembled into supramolecular 1-D chains via I ... pi(Cp) halogen bonds were prepared and structurally characterized. Their structure and conductivity were compared with the ferrocene cocrystals with phenyliodoacetylene (C6H5C2I) and 1,4-di(ethynyliodo) phenylene. Electrical conductivity measurements of the ferrocene-based cocrystals revealed comparatively high electron-hole type conductivity in the ferrocene (FcH)-diiodoacetylene (C2I2) pair, a 3-order decrease in combination with the 1,4-di(ethynyliodo) phenylene linker, and it is virtually extinguished with the monotopic 1,2-phenyliodoacetylene. The increased electric conductivity of compound 1 is rationalized in terms of a weak charge transfer through the I ... pi Cp halogen bonds in the [Cp-Fe-Cp ... I-C C-I ...](n) polymeric chains.
引用
收藏
页码：5114 / 5121
页数：8
相关论文
共 50 条
  • [21] GenX in water: Interactions and self-assembly
    Kancharla, Samhitha
    Choudhary, Aditya
    Davis, Ryan T.
    Dong, Dengpan
    Bedrov, Dmitry
    Tsianou, Marina
    Alexandridis, Paschalis
    JOURNAL OF HAZARDOUS MATERIALS, 2022, 428
  • [22] Nondeterministic self-assembly with asymmetric interactions
    Tesoro, S.
    Gopfrich, K.
    Kartanas, T.
    Keyser, U. F.
    Ahnert, S. E.
    PHYSICAL REVIEW E, 2016, 94 (02)
  • [23] Negative Interactions in Irreversible Self-assembly
    Doty, David
    Kari, Lila
    Masson, Benoit
    ALGORITHMICA, 2013, 66 (01) : 153 - 172
  • [24] Self-assembly in mixtures with competing interactions
    Patsahan, Oksana
    Litniewski, Marek
    Ciach, Alina
    SOFT MATTER, 2021, 17 (10) : 2883 - 2899
  • [25] SYNTHESIS OF ORIENTED CONDUCTING POLYANILINE THIN-FILM VIA MOLECULAR SELF-ASSEMBLY
    CHEN, JY
    CHEN, CY
    WU, CG
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1995, 210 : 151 - COLL
  • [26] Driving molecular self-assembly with π-π interactions
    Harding, Phimphaka
    Harding, David J.
    TRENDS IN CHEMISTRY, 2024, 6 (10): : 575 - 576
  • [27] Curvature and self-assembly of semi-conducting nanoplatelets
    Lilian Guillemeney
    Laurent Lermusiaux
    Guillaume Landaburu
    Benoit Wagnon
    Benjamin Abécassis
    Communications Chemistry, 5
  • [28] Curvature and self-assembly of semi-conducting nanoplatelets
    Guillemeney, Lilian
    Lermusiaux, Laurent
    Landaburu, Guillaume
    Wagnon, Benoit
    Abecassis, Benjamin
    COMMUNICATIONS CHEMISTRY, 2022, 5 (01)
  • [29] Synthesis and self-assembly of conducting polymers at interfaces.
    McCullough, R
    Heuze, K
    Stokes, KA
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2001, 221 : U415 - U416
  • [30] A LAMELLAR CONDUCTING POLYMER BY SELF-ASSEMBLY OF AN ELECTROPOLYMERIZABLE MONOMER
    COLLARD, DM
    FOX, MA
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (24) : 9414 - 9415
12345