Hydrothermal Synthesis, Crystal Structure and-Photoluminescence of a New Two-Dimensional Cadmium(II) Complex [Cd3(HBTA)2(BIPA)3]n

被引:0
作者
Liu Guang-Xiang [1 ]
Xu Yu-Yong [1 ]
Ren Xiao-Ming [1 ]
机构
[1] Anqing Normal Univ, Sch Chem & Chem Engn, Anhui Key Lab Funct Coordinat Cpds, Anqing 246003, Anhui, Peoples R China
关键词
cadmium(II) complex; crystal structure; multicarboxylate ligand; luminescence; METAL-ORGANIC FRAMEWORKS; LUMINESCENT PROPERTIES; COORDINATION POLYMERS; MOLECULAR TECTONICS; 2D LAYER; ZINC(II); SERIES;
D O I
暂无
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The hydrothermal reactions of 5-bromoisophthalic acid (H(2)BIPA), benzotriazole (HBTA) with Cd(NO3)(2)center dot 4H(2)O in basified solvent gave rise to a coordination polymer [Cd-3(HBTA)(2)(BIPA)(3)](n) (1), which has been characterized by elemental analysis, IR and single-crystal X-ray diffraction. Complex 1 presents a two-dimensional (2D) layer network containing the edge-sharing ID -O-Cd-O chains through repetitions of the alternating arrangement of the Cd-3(CO2)(6) cluster and displays strong luminescent emission at room temperature. CCDC: 775284.
引用
收藏
页码:1885 / 1889
页数:5
相关论文
共 25 条
[11]   Controlled assembly of zero-, one- and two-dimensional metal-organic frameworks involving in situ ligand synthesis under different reaction pH [J].
Liu, Guang-Xiang ;
Huang, Rong-Yi ;
Xu, Heng ;
Kong, Xue-Jun ;
Huang, Liang-Fang ;
Zhu, Kun ;
Ren, Xiao-Ming .
POLYHEDRON, 2008, 27 (11) :2327-2336
[12]   Cobalt(ii)-(dpyo)-dicarboxylate networks: Unique H-bonded assembly and rare bridging mode of dpyo in one of them [dpyo = 4,4′-dipyridyl N,N′-dioxide] [J].
Department of Inorganic Chemistry, Indian Association for the Cultivation of Science, Kolkata 7000 32, India ;
不详 ;
不详 .
Dalton Trans., 2007, 14 (1383-1391) :1383-1391
[13]   Toward a molecular photochemical device: A triad for photoinduced charge separation based on a platinum diimine bis(acetylide) chromophore [J].
McGarrah, JE ;
Kim, YJ ;
Hissler, M ;
Eisenberg, R .
INORGANIC CHEMISTRY, 2001, 40 (18) :4510-4511
[14]  
Nakamoto K., 1997, INFRARED RAMAN SPE B
[15]   Microporous metal organic materials: Promising candidates as sorbents for hydrogen storage [J].
Pan, L ;
Sander, MB ;
Huang, XY ;
Li, J ;
Smith, M ;
Bittner, E ;
Bockrath, B ;
Johnson, JK .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (05) :1308-1309
[16]   Rod packings and metal-organic frameworks constructed from rod-shaped secondary building units [J].
Rosi, NL ;
Kim, J ;
Eddaoudi, M ;
Chen, BL ;
O'Keeffe, M ;
Yaghi, OM .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (05) :1504-1518
[17]  
Sheldrick G.M., 1997, SADABS
[18]  
Sheldrick GM, 2015, ACTA CRYSTALLOGR C, V71, P3, DOI [10.1107/S2053229614024218, 10.1107/S0108767307043930, 10.1107/S2053273314026370]
[19]   Benzotriazole controlled unusual building blocks in two zinc complexes and their fluorescence properties [J].
Shen, Yi-Cheng ;
Li, Zhao-Ji ;
Cheng, Jian-Kai ;
Qin, Ye-Yan ;
Yao, Yuan-Gen .
INORGANIC CHEMISTRY COMMUNICATIONS, 2007, 10 (08) :888-890
[20]   Bottom-Up Synthesis of Porous Coordination Frameworks: Apical Substitution of a Pentanuclear Tetrahedral Precursor [J].
Wang, Xin-Long ;
Qin, Chao ;
Wu, Shui-Xing ;
Shao, Kui-Zhan ;
Lan, Ya-Qian ;
Wang, Shuang ;
Zhu, Dong-Xia ;
Su, Zhong-Min ;
Wang, En-Bo .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2009, 48 (29) :5291-5295