Hydrothermal Synthesis, Crystal Structure and-Photoluminescence of a New Two-Dimensional Cadmium(II) Complex [Cd3(HBTA)2(BIPA)3]n

被引：0
作者：
Liu Guang-Xiang [1 ]
Xu Yu-Yong [1 ]
Ren Xiao-Ming [1 ]
机构：
[1] Anqing Normal Univ, Sch Chem & Chem Engn, Anhui Key Lab Funct Coordinat Cpds, Anqing 246003, Anhui, Peoples R China
来源：
CHINESE JOURNAL OF INORGANIC CHEMISTRY | 2010年 / 26卷 / 10期
关键词：
cadmium(II) complex; crystal structure; multicarboxylate ligand; luminescence; METAL-ORGANIC FRAMEWORKS; LUMINESCENT PROPERTIES; COORDINATION POLYMERS; MOLECULAR TECTONICS; 2D LAYER; ZINC(II); SERIES;
D O I：
暂无
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The hydrothermal reactions of 5-bromoisophthalic acid (H(2)BIPA), benzotriazole (HBTA) with Cd(NO3)(2)center dot 4H(2)O in basified solvent gave rise to a coordination polymer [Cd-3(HBTA)(2)(BIPA)(3)](n) (1), which has been characterized by elemental analysis, IR and single-crystal X-ray diffraction. Complex 1 presents a two-dimensional (2D) layer network containing the edge-sharing ID -O-Cd-O chains through repetitions of the alternating arrangement of the Cd-3(CO2)(6) cluster and displays strong luminescent emission at room temperature. CCDC: 775284.
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页码：1885 / 1889
页数：5
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