Aquabis(2,2′-bipyridine-κ2N,N′)copper(II) bis(tetrafluoridoborate)

被引：10

作者：

Yu, Ming-Ming ^{[1
]}

Zhang, Yu-Na ^{[1
]}

Wei, Liu-He ^{[1
]}

机构：

[1] Zhengzhou Univ, Dept Chem, Zhengzhou 450001, Peoples R China

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2007年 / 63卷

关键词：

D O I：

10.1107/S1600536807033557

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

In the title compound, [Cu(C10H8N2)(2)(H2O)](BF4)(2), the Cu-II atom is coordinated by four N atoms and one O atom in a distorted trigonal-bipyramidal geometry. The Cu-N bond lengths are in the range 1.982 ( 3)-2.124 ( 3) angstrom, while the Cu-O distance is 2.035 ( 4) angstrom. The structure is stabilized by O-H center dot center dot center dot F hydrogen bonds between the Cu-II complex and the tetrafluoridoborate anion. The F atoms of one anion are disordered over two positions; the site occupancy ratio is ca 3: 2.

引用

页码：M2380 / U1227

页数：11

共 5 条

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[4] Bis(2,2′-bipyridine-κ2N,N′)copper(I) trifluoromethanesulfonate
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[J]. ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2006, 62 : M620 - M622
[5] Chlorobis(1,10-phenanthroline-κ2N,N′)copper(II) nitrate 4-nitrobenzoic acid monohydrate
Xu, TG
Liu, JG
Xu, DJ
[J]. ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2005, 61 : M787 - M789

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