Structural analysis of phototransformed C60 by vibrational and mass spectroscopy

被引:8
作者
Burger, B
Kuzmany, H
Nguyen, TM
Sitter, H
Walter, M
Martin, K
Mullen, K
机构
[1] Univ Vienna, Inst Mat Phys, A-1090 Vienna, Austria
[2] Univ Linz, Inst Festkorperphys, A-4040 Linz, Austria
[3] MPI Polymerforsch, Mainz, Germany
关键词
fullerene; Raman spectroscopy;
D O I
10.1016/S0008-6223(98)00064-5
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
We report on the structural analysis of the two different phototransformed C-60 materials. The analysis was carried out by comparison of calculated Raman spectra to experimental data and by mass spectroscopy of the different species. It is demonstrated that the mass spectra of C-60 depend strongly on the desorption energy and that most of the polymeric subunits of the transformed material are destroyed upon desorption. (C) 1998 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:661 / 663
页数:3
相关论文
共 3 条
  • [1] Dimer and cluster formation in C-60 photoreaction
    Burger, B
    Winter, J
    Kuzmany, H
    [J]. ZEITSCHRIFT FUR PHYSIK B-CONDENSED MATTER, 1996, 101 (02): : 227 - 233
  • [2] STRUCTURE, STABILITY, AND VIBRATIONAL PROPERTIES OF POLYMERIZED C-60
    POREZAG, D
    PEDERSON, MR
    FRAUENHEIM, T
    KOHLER, T
    [J]. PHYSICAL REVIEW B, 1995, 52 (20): : 14963 - 14970
  • [3] PHOTOINDUCED POLYMERIZATION OF SOLID C-60 FILMS
    RAO, AM
    ZHOU, P
    WANG, KA
    HAGER, GT
    HOLDEN, JM
    WANG, Y
    LEE, WT
    BI, XX
    EKLUND, PC
    CORNETT, DS
    DUNCAN, MA
    AMSTER, IJ
    [J]. SCIENCE, 1993, 259 (5097) : 955 - 957