Selective oxidation of (hetero)sulfides with molecular oxygen under clean conditions

被引:120
作者
Liu, Kai-Jian [1 ]
Deng, Ji-Hui [1 ]
Yang, Jie [1 ]
Gong, Shao-Feng [1 ]
Lin, Ying-Wu [2 ]
He, Jun-Yi [3 ]
Cao, Zhong [3 ]
He, Wei-Min [1 ]
机构
[1] Hunan Univ Sci & Engn, Dept Chem, Yongzhou 425100, Peoples R China
[2] Univ South China, Sch Chem & Chem Engn, Hengyang 421001, Peoples R China
[3] Changsha Univ Sci & Technol, Hunan Prov Key Lab Mat Protect Elect Power & Tran, Changsha 410114, Peoples R China
关键词
METAL-FREE; AEROBIC OXIDATIONS; SULFOXIDES; SULFIDES; CYCLIZATION; INSERTION; SULFONES; ALCOHOLS; ELECTRON; AMBIENT;
D O I
10.1039/c9gc03713f
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The development of eco-friendly and switchable catalytic systems for the conversion of a sole raw-material into distinct high-value products is a particularly attractive concept and a daunting synthetic challenge. In the present work, the first example of efficient and selective oxidation of sulfides to sulfones and sulfoxides using molecular oxygen under clean conditions was established.
引用
收藏
页码:433 / 438
页数:6
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