Cyclodextrins as Mass Transfer Additives in Aqueous Organometallic Catalysis

被引:42
作者
Bricout, H. [1 ,2 ,3 ]
Hapiot, F. [1 ,2 ,3 ]
Ponchel, A. [1 ,2 ,3 ]
Tilloy, S. [1 ,2 ,3 ]
Monflier, E. [1 ,2 ,3 ]
机构
[1] Univ Artois, UCCS, Fac Sci, F-62307 Lens, France
[2] Univ Lille, F-59000 Lille, France
[3] CNRS, UMR 8181, F-59650 Villeneuve Dascq, France
关键词
Cyclodextrins; water; organometallic catalysis; water-soluble phosphines; host-guest chemistry; recognition; MODIFIED BETA-CYCLODEXTRINS; HOST-GUEST CHEMISTRY; HIGHER ALPHA-OLEFINS; BIPHASIC HYDROFORMYLATION; METHYLATED CYCLODEXTRINS; RHODIUM COMPLEXES; 2-PHASE HYDROFORMYLATION; MOLECULAR RECOGNITION; WACKER OXIDATION; MONOSULFONATED TRIPHENYLPHOSPHINE;
D O I
10.2174/138527210791616920
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
During the past fifteen years, the use of chemically modified cyclodextrins (CDs) in aqueous organometallic catalysis has significantly contributed to enlarge the application field of biphasic processes in chemistry. In this paper, we describe how these supramolecular receptors became one of the most efficient solutions to solve mass transfer problems in aqueous organometallic catalysis. The scientific gaps that have been cleared to explain the exact role of the CDs in these biphasic systems are especially emphasized. In particular, the impact of supramolecular interactions between chemically modified CDs and substrates, water soluble ligands or organometallic catalysts is addressed for a better understanding of the recognition processes involved in the catalytic reactions.
引用
收藏
页码:1296 / 1307
页数:12
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