Synthesis of Redox-Active Photochromic Phenanthrene Derivatives

被引：2

作者：

Chatir, Elarbi ^{[1
]}

Boggio-Pasqua, Martial ^{[2
]}

Loiseau, Frederique ^{[1
]}

Philouze, Christian ^{[1
]}

Royal, Guy ^{[1
]}

Cobo, Saioa ^{[1
,3
]}

机构：

[1] Univ Grenoble Alpes, CNRS, DCM, F-38000 Grenoble, France

[2] Univ Toulouse 3 Paul Sabatier, CNRS, LCPQ, UMR 5626, 118 Route Narbonne, F-31062 Toulouse, France

[3] Inst Univ France, 1 Rue Descartes, F-75231 Paris, France

来源：

CHEMISTRY-A EUROPEAN JOURNAL | 2022年 / 28卷 / 07期

关键词：

DFT calculations; dithienylethene; phenanthrene; photochromism; redox properties; MOLECULAR-ORBITAL METHODS; REVERSIBLE PHOTOCYCLIZATION; BASIS-SETS; CRYSTALS; SYSTEMS;

D O I：

10.1002/chem.202103755

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A phenanthrene unit has been functionalized by several methylthiophene units in order to bring it a photochromic behavior. These compounds were characterized by NMR, absorption and emission spectroscopies, theoretical calculations as well as cyclic voltammetry. The association of a phenanthrene group with a photochromic center could open the door to a new generation of organic field-effect transistors.

引用

页数：9

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