Synthesis of Redox-Active Photochromic Phenanthrene Derivatives

被引：2
|
作者：
Chatir, Elarbi [1 ]
Boggio-Pasqua, Martial [2 ]
Loiseau, Frederique [1 ]
Philouze, Christian [1 ]
Royal, Guy [1 ]
Cobo, Saioa [1 ,3 ]
机构：
[1] Univ Grenoble Alpes, CNRS, DCM, F-38000 Grenoble, France
[2] Univ Toulouse 3 Paul Sabatier, CNRS, LCPQ, UMR 5626, 118 Route Narbonne, F-31062 Toulouse, France
[3] Inst Univ France, 1 Rue Descartes, F-75231 Paris, France
来源：
CHEMISTRY-A EUROPEAN JOURNAL | 2022年 / 28卷 / 07期
关键词：
DFT calculations; dithienylethene; phenanthrene; photochromism; redox properties; MOLECULAR-ORBITAL METHODS; REVERSIBLE PHOTOCYCLIZATION; BASIS-SETS; CRYSTALS; SYSTEMS;
D O I：
10.1002/chem.202103755
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A phenanthrene unit has been functionalized by several methylthiophene units in order to bring it a photochromic behavior. These compounds were characterized by NMR, absorption and emission spectroscopies, theoretical calculations as well as cyclic voltammetry. The association of a phenanthrene group with a photochromic center could open the door to a new generation of organic field-effect transistors.
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页数：9
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