Unreactive C-N Bond Activation of Anilines via Photoinduced Aerobic Borylation

被引：14

作者：

Ji, Shuohan ^{[1
,2
,3
]}

Qin, Shengxiang ^{[1
,2
,3
]}

Yin, Chunyu ^{[1
,2
]}

Luo, Lu ^{[1
,2
]}

Zhang, Hua ^{[1
,2
,3
]}

机构：

[1] South Cent Univ Nationalities, Key Lab Catalysis & Energy Mat Chem, Minist Educ, Wuhan 430074, Peoples R China

[2] South Cent Univ Nationalities, Hubei Key Lab Catalysis & Mat Sci, Wuhan 430074, Peoples R China

[3] Nanchang Univ, Coll Chem, Nanchang 330031, Jiangxi, Peoples R China

来源：

ORGANIC LETTERS | 2022年 / 24卷 / 01期

基金：

中国国家自然科学基金;

关键词：

CARBON-NITROGEN BONDS; CATALYZED CLEAVAGE; ARYL; SALTS; ORGANOBORANES; DERIVATIVES; CONVERSION; AMINES; OXYGEN;

D O I：

10.1021/acs.orglett.1c03590

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Unreactive C-N bond activation of anilines was achieved by photoinduced aerobic borylation. A diverse range of tertiary and secondary anilines were converted to aryl boronate esters in moderate to good yields with wide functional group tolerance under simple and ambient photochemical conditions. This transformation achieved the direct and facile C-N bond activation of unreactive anilines, providing a convenient and practical route transforming widely available anilines into useful aryl boronate esters.

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收藏

页码：64 / 68

页数：5

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