Regioselective homologation of bis(boronate) intermediates derived from rhodium-catalyzed diboration of simple alkenes

被引：20
作者：
Kalendra, DM [1 ]
Dueñes, RA [1 ]
Morken, JP [1 ]
机构：
[1] Univ N Carolina, Dept Chem, Chapel Hill, NC 27599 USA
来源：
SYNLETT | 2005年 / 11期
关键词：
boron; asymmetric catalysis; silicon; regioselectivity; alkenes;
D O I：
10.1055/s-2005-869873
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Regioselective homologation of alkyl-1,2-bis(catecholboronates) may be accomplished by treatment of these reactive intermediates with TMSCHN2. A convenient process is reported where alkene diboration and the subsequent homologation reaction are accomplished in the same reaction flask.
引用
收藏
页码：1749 / 1751
页数：3
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