Influence of the interfacial reaction on interfacial adhesion in polyarylacetylene resin-silica glass composites

被引：1
作者：
Jiang, Z. X. [1 ]
Huang, Y. D. [1 ]
Liu, L. [1 ]
机构：
[1] Harbin Inst Technol, Fac Sci, Dept Appl Chem, Harbin 150001, Peoples R China
来源：
JOURNAL OF ADHESION SCIENCE AND TECHNOLOGY | 2007年 / 21卷 / 14期
基金：
美国国家科学基金会; 中国国家自然科学基金;
关键词：
polyarylacetylene resin; interfacial reaction; interfacial adhesion; infrared spectroscopy; X-ray photoelectron spectroscopy;
D O I：
10.1163/156856107782313601
中图分类号：
TQ [化学工业];
学科分类号：
0817 ;
摘要：
The influence of interfacial reaction on interfacial adhesion in silica glass/polyarylacetylene resin composites was studied. In order to achieve chemical reaction at the interface, vinyltrimethoxysilane was grafted onto silica glass surface to react with polyarylacetylene resin. The reaction between polyarylacetylene resin and vinyltrimethoxysilane was proved based on the model reaction between phenylacetylene and vinyltrimethoxysilane. At the same time, the modified silica glass surface characteristics were evaluated by contact-angle measurements and surface energy determination. The interfacial adhesion in silica glass/polyarylacetylene resin composites was evaluated by shear strength testing and fracture morphology analysis. It was concluded that polyarylacetylene resin reacted with vinyltrimethoxysilane. Furthermore, due to the reaction between polyarylacetylene resin and vinyltrimethoxysilane at the interface, the interfacial adhesion in composites was significantly increased. The improvement in interfacial adhesion was solely attributed to the interfacial reaction.
引用
收藏
页码：1395 / 1405
页数：11
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