Water transport through Nafion 112 membrane in DMFCs

被引:116
作者
Lu, GQ [1 ]
Liu, FQ
Wang, CY
机构
[1] Penn State Univ, Electrochem Engine Ctr, Dept Mech & Nucl Engn, University Pk, PA 16802 USA
[2] Penn State Univ, Electrochem Engine Ctr, Dept Mat Sci & Engn, University Pk, PA 16802 USA
关键词
D O I
10.1149/1.1825312
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
Water management has emerged as a significant challenge in portable direct methanol fuel cells, DMFCs. Excessive water crossover through the membrane causes water loss in the anode and flooding in the cathode. We report a novel DMFC design based on Nafion 112 and a cathode gas-diffusion layer coated with a microporous layer. This DMFC operated with ambient air yielded a stable power density of 56 mW/cm(2) at 60 degrees C, while the net water transport coefficient was only 0.64 compared to a typical value of 3 for Nafion 117 membranes. In addition, the fuel efficiency was about 74-92%. (C) 2004 The Electrochemical Society.
引用
收藏
页码:A1 / A4
页数:4
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