共 41 条
Carbenoxolone as a Multifunctional Vehicle for Electrodeposition of Materials
被引:1
作者:
Liu, Xinqian
[1
]
Veldhuis, Stephen
[2
]
Mathews, Ritch
[3
]
Zhitomirsky, Igor
[1
]
机构:
[1] McMaster Univ, Dept Mat Sci & Engn, Hamilton, ON L8S 4L7, Canada
[2] McMaster Univ, Dept Mech Engn, Hamilton, ON L8S 4L7, Canada
[3] Adv Ceram Corp, 2536 Bristol Circle, Oakville, ON L6H 5S1, Canada
来源:
APPLIED SCIENCES-BASEL
|
2021年
/
11卷
/
19期
基金:
加拿大自然科学与工程研究理事会;
关键词:
electrophoretic deposition;
film;
diamond;
polytetrafluoroethylene;
graphene;
composite;
dispersant;
corrosion protection;
ELECTROPHORETIC DEPOSITION;
MANGANESE OXIDE;
ELECTROCHEMICAL DEPOSITION;
GRAPHENE NANOPLATELETS;
SURFACE MODIFICATION;
COMPOSITES;
D O I:
10.3390/app11199110
中图分类号:
O6 [化学];
学科分类号:
0703 ;
摘要:
This investigation describes for the first time the application of carbenoxolone for electrophoretic deposition (EPD) of different carbon materials, polytetrafluoroethylene (PTFE) and their composite films. Carbenoxolone is a versatile biosurfactant, which adsorbs on materials due to its amphiphilic structure and allows their charging and dispersion. Moreover, carbenoxolone exhibits film-forming properties, which are investigated in experiments on EPD of films using water and ethanol-water solvents. The new deposition process is monitored in situ and the deposition yield and film microstructure are analyzed at different conditions. The EPD mechanism of materials involves electrode reactions of the carbenoxolone surfactant. The data of potentiodynamic studies coupled with the results of impedance spectroscopy show that PTFE films can be applied to protect metals from corrosion. Electron microscopy, electrochemical techniques and modeling are used for analysis of the microstructure and porosity of films prepared at different conditions. Carbenoxolone is applied as a co-surfactant for the EPD of composites.
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页数:10
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