Cyclocondensation of 5-chloro-4-formylpyrrole-3-carboxylates with arylamines. Synthesis and fluorescent properties of pyrrolo[2,3-b]quinoline-3-carboxylates and their benzo[f] analogs

被引：0

作者：

Grozav, Alina N. ^{[1
]}

Fedoriv, Mariana Z. ^{[2
]}

Chornous, Vitaliy A. ^{[1
]}

Kemskiy, Sergiy, V ^{[3
]}

Polishchuk, Vladislav M. ^{[3
]}

Shandura, Nikolay P. ^{[3
]}

Rusanov, Eduard B. ^{[3
]}

Vovk, Mikhailo V. ^{[3
]}

机构：

[1] Bukovinian State Med Univ, 2 Teatralna Sq, UA-58000 Chernovtsy, Ukraine

[2] Ivano Frankivsk Natl Med Univ, 2 Galytska St, UA-76018 Ivano Frankivsk, Ukraine

[3] Natl Acad Sci Ukraine, Inst Organ Chem, 5 Murmanska St, UA-02094 Kiev, Ukraine

来源：

CHEMISTRY OF HETEROCYCLIC COMPOUNDS | 2021年 / 57卷 / 10期

关键词：

arylamines; benzo[f]pyrrolo[2,3-b]quinoline-10-carboxylates; benzo[f]pyrrolo[2,3-b]quinoline-10-carboxylic acids; 5-chloro-4-formylpyrrole-3-carboxylates; pyrrolo[2,3-b]quinoline-3-carboxylates; pyrrolo[2,3-b]quinoline-3-carboxylic acids; alkaline hydrolysis; cyclocondensation; fluorescent properties; DERIVATIVES; PYRROLOQUINOLINES; DYES;

D O I：

10.1007/s10593-021-03017-y

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

5-Chloro-4-formylpyrrole-3-carboxylates react with anilines or beta-naphthylamine when heated in DMF under reflux to form ethyl pyrrolo[2,3-b]quinoline-3-carboxylates or their benzo[f] analogs, which exhibit moderate fluorescent properties. The corresponding carboxylic acids were obtained by alkaline hydrolysis of the synthesized carboxylates.

引用

页码：1024 / 1030

页数：7

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