Direct hydrogenolysis of biomass-derived furans over Pt/CeO2 catalyst with high activity and stability

被引：39

作者：

Tong, Tao ^{[1
]}

Xia, Qineng ^{[1
]}

Liu, Xiaohui ^{[1
]}

Wang, Yanqin ^{[1
]}

机构：

[1] East China Univ Sci & Technol, Shanghai Key Lab Funct Mat Chem, Res Inst Ind Catalysis, Sch Chem & Mol Engn, Shanghai 200237, Peoples R China

来源：

CATALYSIS COMMUNICATIONS | 2017年 / 101卷

基金：

中国博士后科学基金;

关键词：

Hydrogenolysis; Furfural; 1,2-Pentandiol; Pt/CeO2; Ring opening; MILD CONDITIONS; FURFURYL ALCOHOL; HYDROGENATION; CONVERSION; CHEMICALS; 1,5-PENTANEDIOL; TRANSFORMATION; 2,5-DIMETHYLFURAN; 1,2-PENTANEDIOL; 1,6-HEXANEDIOL;

D O I：

10.1016/j.catcom.2017.08.005

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Conversion of biomass -derived furans to fine chemicals has raised wide interests recently. Here we show direct hydrogenolysis of furans to corresponding alcohols in i-propanol (i-PrOH) over a highly active and stable Pt/CeO2 catalyst. CeO2 as the support shows superior catalytic performance in comparison to other supports. The hydrogenolysis of furfural to 1,2-pentandiol (1,2-PeD) can be realized in high yields (up to 59.9%) under mild conditions. Moreover, this catalytic system shows good recyclability with no obvious activity loss after five successive runs, which goes a step further towards the industrial application of heterogeneous catalysts for fine chemical production from biomass.

引用

页码：129 / 133

页数：5

共 35 条

[1] Solvent effects in the liquid phase hydrodeoxygenation of methyl propionate over a Pd(111) catalyst model
Behtash, Sina
Lu, Jianmin
Walker, Eric
Mamun, Osman
Heyden, Andreas
[J]. JOURNAL OF CATALYSIS, 2016, 333 : 171 - 183
[2] Chemicals from Biomass: Combining Ring-Opening Tautomerization and Hydrogenation Reactions to Produce 1,5-Pentanediol from Furfural
Brentzel, Zachary J.
Barnett, Kevin J.
Huang, Kefeng
Maravelias, Christos T.
Dumesic, James A.
Huber, George W.
[J]. CHEMSUSCHEM, 2017, 10 (07) : 1351 - 1355
[3] Caprolactam from Renewable Resources: Catalytic Conversion of 5-Hydroxymethylfurfural into Caprolactone
Buntara, Teddy
Noel, Sebastien
Phua, Pim Huat
Melian-Cabrera, Ignacio
de Vries, Johannes G.
Heeres, Hero J.
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2011, 50 (31) : 7083 - 7087
[4] C-O bond hydrogenolysis of cyclic ethers with OH groups over rhenium-modified supported iridium catalysts
Chen, Kaiyou
Mori, Kazuma
Watanabe, Hideo
Nakagawa, Yoshinao
Tomishige, Keiichi
[J]. JOURNAL OF CATALYSIS, 2012, 294 : 171 - 183
[5] Catalytic applications of layered double hydroxides: recent advances and perspectives
Fan, Guoli
Li, Feng
Evans, David G.
Duan, Xue
[J]. CHEMICAL SOCIETY REVIEWS, 2014, 43 (20) : 7040 - 7066
[6] Haider MH, 2015, NAT CHEM, V7, P1028, DOI [10.1038/NCHEM.2345, 10.1038/nchem.2345]
[7] Reaction Pathways and Intermediates in Selective Ring Opening of Biomass-Derived Heterocyclic Compounds by Iridium
Jenness, Glen R.
Wan, Weiming
Chen, Jingguang G.
Vlachos, Dionisios G.
[J]. ACS CATALYSIS, 2016, 6 (10): : 7002 - 7009
[8] Promoting effect of Mo on the hydrogenolysis of tetrahydrofurfuryl alcohol to 1,5-pentanediol over Rh/SiO2
Koso, Shuichi
Ueda, Naoyuki
Shinmi, Yasunori
Okumura, Kazu
Kizuka, Tokushi
Tomishige, Keiichi
[J]. JOURNAL OF CATALYSIS, 2009, 267 (01) : 89 - 92
[9] Chemoselective hydrogenolysis of tetrahydrofurfuryl alcohol to 1,5-pentanediol
Koso, Shuichi
Furikado, Ippei
Shimao, Akira
Miyazawa, Tomohisa
Kunimori, Kimio
Tomishige, Keiichi
[J]. CHEMICAL COMMUNICATIONS, 2009, (15) : 2035 - 2037
[10] Lignin Depolymerization with Nitrate-Intercalated Hydrotalcite Catalysts
Kruger, Jacob S.
Cleveland, Nicholas S.
Zhang, Shuting
Katahira, Rui
Black, Brenna A.
Chupka, Gina M.
Lammens, Tijs
Hamilton, Phillip G.
Biddy, Mary J.
Beckham, Gregg T.
[J]. ACS CATALYSIS, 2016, 6 (02): : 1316 - 1328

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