The synthesis and X-ray structure of [Sr2(OSiPh3)4(NH3)5]•0.5C7H8

被引：4
|
作者：
Baxter, IA
Darr, JA
Drake, SR
Hursthouse, MB
Malik, KMA
Mingos, DMP
机构：
[1] Univ Nottingham, Dept Chem, Nottingham NG7 2RD, England
[2] Univ Wales, Dept Chem, Cardiff CF1 3TB, S Glam, Wales
[3] Univ London Imperial Coll Sci Technol & Med, Dept Chem, London SW7 2AY, England
来源：
JOURNAL OF CHEMICAL CRYSTALLOGRAPHY | 1998年 / 28卷 / 03期
基金：
英国工程与自然科学研究理事会;
关键词：
strontium; triphenylsiloxy; crystal structure; ammonia;
D O I：
10.1023/A:1022430612896
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The title complex [Sr-2(OSiPh3)(4)(NH3)(5)]. 0.5C(7)H(8) was prepared by the reaction of strontium metal granules with triphenylsilanol in an ammoniacal-toluene solution at -40 degrees C. It crystallizes in monoclinic space group P2(1)/n with a = 14.465(3), b = 20.715 (6), c = 25.199(6) Angstrom, beta = 95.98(2)degrees, and Z = 4. The complex has a dimeric structure with one terminal and three bridging triphenylsiloxy ligands, the remaining coordination sites being occupied by five ammonia molecules. The central Sr2O4N5 moiety adopts a distorted M2X9 face-sharing bioctahedral arrangement.
引用
收藏
页码：221 / 226
页数：6
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