Organosulfonate Counteranions-A Trapped Coordination Polymer as a High-Output Triboelectric Nanogenerator Material for Self-Powered Anticorrosion

被引:48
|
作者
Zhang, Yingying [1 ]
Wu, Jiarui [1 ]
Cui, Siwen [1 ]
Wei, Wutao [1 ]
Chen, Weihua [4 ]
Pang, Rui [2 ,3 ]
Wu, Zijie [5 ]
Mi, Liwei [1 ]
机构
[1] Zhongyuan Univ Technol, Ctr Adv Mat Res, Zhengzhou 450007, Henan, Peoples R China
[2] Zhengzhou Univ, Int Lab Quantum Funct Mat Henan, Zhengzhou 450001, Henan, Peoples R China
[3] Zhengzhou Univ, Sch Phys & Engn, Zhengzhou 450001, Henan, Peoples R China
[4] Zhengzhou Univ, Coll Chem & Mol Engn, Zhengzhou 450001, Henan, Peoples R China
[5] Univ Manchester, North West Composites Ctr, Sch Mat, Manchester M13 9PL, Lancs, England
基金
中国国家自然科学基金;
关键词
cathodic protection; cobalt(II); coordination polymers; organosulfonate; triboelectric nanogenerators; METAL-ORGANIC FRAMEWORKS; PROTON CONDUCTION; CHEMISTRY; DRIVEN; CO2;
D O I
10.1002/chem.201904873
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Selection of the friction electrode materials is crucial to the performance of a triboelectric nanogenerator (TENG). In the present study, a metal-organic coordination complex containing organosulfonate counteranions with electron-donating ability was synthesized through the coordination-driven self-assembly approach under mild reaction conditions and was chosen as a positive electrode material to construct a triboelectric nanogenerator, exhibiting high-output performance with a peak value of short circuit current density of 98.6 mu A and an output voltage of 1180 V. As a practical application, it was shown to light up 1488 commercial green LEDs and power an anticorrosion system device to protect metals from corrosion.
引用
收藏
页码:584 / 591
页数:8
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